东华大学学报(英文版)
東華大學學報(英文版)
동화대학학보(영문판)
JOURNAL OF DONGHUA UNIVERSITY
2003年
1期
54-57
,共4页
Activation energy%exponent%maximummass loss rate%thermal degradation
The derivative expressions between activation energy (E) and the temperature at the maximum mass loss rate(Tmax) and between activation energy (E) and exponent (N) were deduced in the light of Arrhenius theory. It was found that the increase of activation energy results in the decrease of exponent and the increase of Tmax. The kinetic parameters were involved in the analysis of the thermal degradation of several polymers. The degradation kinetics of these polymers well complied with the prediction of the derivative expressions for the polymer degradation with single mechanism dominated.