郑州大学学报(工学版)
鄭州大學學報(工學版)
정주대학학보(공학판)
JOURNAL OF ZHENGZHOU UNIVERSITY(ENGINEERING SCIENCE)
2010年
1期
61-64
,共4页
雒廷亮%王钰%杨丽萍%宋文建%刘国际
雒廷亮%王鈺%楊麗萍%宋文建%劉國際
락정량%왕옥%양려평%송문건%류국제
间十五烷基酚%正丁醇%密度%黏度
間十五烷基酚%正丁醇%密度%黏度
간십오완기분%정정순%밀도%점도
3-pentadecylphenol%n-butanol%density%viscosity
利用比重瓶和乌氏粘度计,测定了283.15K~313.15K条件下,间十五烷基酚的正丁醇溶液在不同组成下的密度与黏度.结果表明,在测定范围内,密度与黏度均随着温度的升高而降低,随着间十五烷基酚质量摩尔浓度的增大而增大,同时也计算了间十五烷基酚正丁醇溶液的表观摩尔体积.用VTF方程对数据关联,分别拟合得到两个关联方程,总的平均相对偏差为1.32%,标准偏差为1.67%.
利用比重瓶和烏氏粘度計,測定瞭283.15K~313.15K條件下,間十五烷基酚的正丁醇溶液在不同組成下的密度與黏度.結果錶明,在測定範圍內,密度與黏度均隨著溫度的升高而降低,隨著間十五烷基酚質量摩爾濃度的增大而增大,同時也計算瞭間十五烷基酚正丁醇溶液的錶觀摩爾體積.用VTF方程對數據關聯,分彆擬閤得到兩箇關聯方程,總的平均相對偏差為1.32%,標準偏差為1.67%.
이용비중병화오씨점도계,측정료283.15K~313.15K조건하,간십오완기분적정정순용액재불동조성하적밀도여점도.결과표명,재측정범위내,밀도여점도균수착온도적승고이강저,수착간십오완기분질량마이농도적증대이증대,동시야계산료간십오완기분정정순용액적표관마이체적.용VTF방정대수거관련,분별의합득도량개관련방정,총적평균상대편차위1.32%,표준편차위1.67%.
Densities and viscosities of 3-pentadecylphenol + n-butanol system at 283.15K ~ 313. 15K were measured by calibrated pyenometer and Ubbelohde-type capillary viseometer. The results show that: both den-sities and viscosities decrease while the temperature increases, and increase with increasing molalities of 3-pentadeeylphenol. At the same time, the apparent molar volumes of 3-pentadeeylphenol in n-butanol is also calculated. The experimental data were regressed with VTF equation, the total average relative deviation is 1.32% , and the total standard deviation is 1.67%.