CAJ | 학술논문

合成了一种新的配位化合物(苄基三乙基铵)双(1,3三硫杂环戊烯-2-硫酮-4,5二硫基)-金(BTEAADT).利用旋涂技术制备了该材料与聚甲基丙烯酸甲酯(PMMA)掺杂的复合薄膜,该材料在复合薄膜中的质量分数为1%.采用Z扫描方法.分别测试了该材料的乙腈溶液和该材料与PMMA复合薄膜在波长为1064 nm,脉宽为20 ps条件下的三阶非线性光学特性.同时还研究了复合薄膜的线性光学性质.Z扫描的结果表明,复合薄膜和该材料的乙腈溶液都具有自散焦效应,非线性折射率都是负值.在实验条件下,两者的非线性吸收效应都是可以忽略的.经过计算得出溶液样品的非线性折射率为-1.459x10-18m2·W-1,复合薄膜样品的非线性折射率为-3.978x10-15 m2·W-1.该材料在1064 nm处的非线性光学器件方面有潜在应用价值.
합성료일충신적배위화합물(변기삼을기안)쌍(1,3삼류잡배무희-2-류동-4,5이류기)-금(BTEAADT).이용선도기술제비료해재료여취갑기병희산갑지(PMMA)참잡적복합박막,해재료재복합박막중적질량분수위1%.채용Z소묘방법.분별측시료해재료적을정용액화해재료여PMMA복합박막재파장위1064 nm,맥관위20 ps조건하적삼계비선성광학특성.동시환연구료복합박막적선성광학성질.Z소묘적결과표명,복합박막화해재료적을정용액도구유자산초효응,비선성절사솔도시부치.재실험조건하,량자적비선성흡수효응도시가이홀략적.경과계산득출용액양품적비선성절사솔위-1.459x10-18m2·W-1,복합박막양품적비선성절사솔위-3.978x10-15 m2·W-1.해재료재1064 nm처적비선성광학기건방면유잠재응용개치.
We prepared a new crystalline nonlinear optical coordination compound, benzyltriethylamine bis (2-thioxo-1,3-dithiole-4,5-dithiolato) aurate(lll) (BTEAADT). A BTEAADT-doped poly(methyl methacrylate) (PMMA) thin film with a mass fraction of 1% was prepared by spin-coating. The third-order nonlinear optical properties of BTEAADT in acetonitrile and a BTEAADT-doped PMMA film were investigated using the laser Z-scan technique with 20 ps pulses at 1064 nm. The linear optical properties of the polymer thin film were also studied. The Z-scan spectra revealed that the polymer thin film sample possessed negative nonlinear refraction and exhibited a similar self-defocusing effect to that found for the solution. In addition, nonlinear absorption was negligible for both systems under the experimental conditions used. The nonlinear refractive index was calculated to be -1.459x10-18m2· W-1 for the solution sample and -3.978x 10-15m2·W-1 for the film. These results suggest that this material is a promising candidate for application in nonlinear optical devices such as all-optical switching manufacture at 1064 nm.