长治学院学报
長治學院學報
장치학원학보
JOURNAL OF CHANGZHI UNIVERSITY
2013年
2期
21-24
,共4页
王志军%逯美红%周小芳%王铁云
王誌軍%逯美紅%週小芳%王鐵雲
왕지군%록미홍%주소방%왕철운
乙烯气体%拉曼光谱%密度泛函理论%振动模式
乙烯氣體%拉曼光譜%密度汎函理論%振動模式
을희기체%랍만광보%밀도범함이론%진동모식
Ethylene Gas%Raman spectra%DFT%vibrational mode
首次利用激光拉曼技术对微量乙烯气体进行测试和分析,得到500 cm-1~3500 cm-1内乙烯气体的拉曼光谱。结果表明,乙烯气体的拉曼光谱有明显特征峰,这一性质为进一步研究果蔬散发乙烯气体的检测提供了依据。
首次利用激光拉曼技術對微量乙烯氣體進行測試和分析,得到500 cm-1~3500 cm-1內乙烯氣體的拉曼光譜。結果錶明,乙烯氣體的拉曼光譜有明顯特徵峰,這一性質為進一步研究果蔬散髮乙烯氣體的檢測提供瞭依據。
수차이용격광랍만기술대미량을희기체진행측시화분석,득도500 cm-1~3500 cm-1내을희기체적랍만광보。결과표명,을희기체적랍만광보유명현특정봉,저일성질위진일보연구과소산발을희기체적검측제공료의거。
The Raman spectra of ethylene gas were obtained and investigated between by Raman-spec-troscopy technique for the first time. It showed that ethylene had obvious characteristic Raman peaks. This property provided for the further study of fruit and vegetable with ethylene gas detection. In addition , the den-sity functional theory (DFT) with B3LYP complex function was used to calculate the geometric structure and Raman vibrational frequencies of ethylene gas, and the Raman spectra features and vibrational modes were as-signed based on DFT calculation. The theoretical calculation results agreed well with the experimental results better. The accuracy of simulation results demonstrated that Raman-spectroscopy technique was applicable for detection of ethylene gas feasibility.