CAJ | 학술논문

　　通过丙烯酸六氟丁酯和甲基封端的N-β-氨乙基-γ-氨丙基甲基硅油侧链伯氨基的加成反应，制备了氟烷基改性氨基硅油；并将其用于涤纶染色织物的增深整理。采用红外光谱表征了氟烷基改性氨基硅油的结构，研究了氟含量、整理剂浓度、乳液粒径对织物增深效果的影响。结果表明，随着氟含量的提高，织物表观色深提高；进一步提高氟含量，会影响硅油在织物表面的成膜性，增深效果不明显。将两种不同粒径的乳液复配使用，能提升涤纶织物的增深性能，将氟烷基改性氨基硅油乳液质量浓度分别为10 g/L和50 g/L的氟烷基改性氨基硅油乳液按1∶1的质量复配使用时，和未处理样相比，织物表观色深提升达到17.42％；经氟烷基改性氨基硅油整理的织物的干、湿摩擦牢度有所下降，但织物的耐水洗色牢度并未发生改变。
　　통과병희산륙불정지화갑기봉단적N-β-안을기-γ-안병기갑기규유측련백안기적가성반응，제비료불완기개성안기규유；병장기용우조륜염색직물적증심정리。채용홍외광보표정료불완기개성안기규유적결구，연구료불함량、정리제농도、유액립경대직물증심효과적영향。결과표명，수착불함량적제고，직물표관색심제고；진일보제고불함량，회영향규유재직물표면적성막성，증심효과불명현。장량충불동립경적유액복배사용，능제승조륜직물적증심성능，장불완기개성안기규유유액질량농도분별위10 g/L화50 g/L적불완기개성안기규유유액안1∶1적질량복배사용시，화미처리양상비，직물표관색심제승체도17.42％；경불완기개성안기규유정리적직물적간、습마찰뇌도유소하강，단직물적내수세색뇌도병미발생개변。
A fluoroalkyl-modified amino-silicone fluid was synthesized via addition reaction between hexafluorobutyl acrylate and methyl-terminated aminoethyl ammonium propyl methyl silicone fluid of side chain primary amine.The modified amino-silicone fluid was applied for deepening finishing of colored polyester fab-ric.The product was characterized by FTIR, and the effects of the depth effect including fluorine content , the concentration of finishing agent and particle size of emulsion were investigated .The results showed that with the increase of fluorine content, the K/S values went upward.Further increase of fluorine content affected the properties of film that formed on the surface of fabric , and the depth effect was not obvious .Using a mixed e-mulsion of two emulsions with different particle sizes improved the deep dyeing effect on polyester fabric .Com-pared with that of the untreated fabric , the K/S value of the treated fabrics were increased up to 17.42%when the fabrics was treated with the mixture of the fluoroalkyl-modified amino-silicone fluid emulsions at 10 g/L and 50 g/L respectively with mass ratio of 1∶1.The dry and wet rubbing fatness of the colored polyester fabric treated with fluoroalkyl-modified amino-silicone fluid were decreased, but its washable color fatness kept the same.