采矿与安全工程学报
採礦與安全工程學報
채광여안전공정학보
JOURNAL OF MINING AND SAFETY ENGINEERING
2013年
3期
415-420
,共6页
突出煤%孔隙结构%吸附特性%吸附-解吸等温线%实验研究
突齣煤%孔隙結構%吸附特性%吸附-解吸等溫線%實驗研究
돌출매%공극결구%흡부특성%흡부-해흡등온선%실험연구
outburst coal%pore structure%adsorption property%isotherm curve of adsorption-desorption%experimental study
为了完善贵州区内突出煤的孔隙结构和吸附特性等物理特性,基于煤的孔隙结构和吸附特性对于瓦斯(煤层气)抽采与防治煤与瓦斯突出的重要性,采用相关仪器测定了贵州突出煤的孔隙结构和吸附特性,并分析了实验结果。结果表明:突出煤样平行层理表面均存在一定数量的晶体物质和微孔;突出煤样垂直节理表面可见一道或几道平行或交叉的且大小不一的裂隙;突出煤样的孔隙或裂隙孔径大部分在0~10 nm之间,孔径为3~5 nm的微孔在煤样中最为丰富,为瓦斯(煤层气)主要吸附空间;当相对压力达到0.8左右时,瓦斯吸附量会急剧上升;突出煤样瓦斯吸附量存在较大差异,孔容大的吸附量大。
為瞭完善貴州區內突齣煤的孔隙結構和吸附特性等物理特性,基于煤的孔隙結構和吸附特性對于瓦斯(煤層氣)抽採與防治煤與瓦斯突齣的重要性,採用相關儀器測定瞭貴州突齣煤的孔隙結構和吸附特性,併分析瞭實驗結果。結果錶明:突齣煤樣平行層理錶麵均存在一定數量的晶體物質和微孔;突齣煤樣垂直節理錶麵可見一道或幾道平行或交扠的且大小不一的裂隙;突齣煤樣的孔隙或裂隙孔徑大部分在0~10 nm之間,孔徑為3~5 nm的微孔在煤樣中最為豐富,為瓦斯(煤層氣)主要吸附空間;噹相對壓力達到0.8左右時,瓦斯吸附量會急劇上升;突齣煤樣瓦斯吸附量存在較大差異,孔容大的吸附量大。
위료완선귀주구내돌출매적공극결구화흡부특성등물리특성,기우매적공극결구화흡부특성대우와사(매층기)추채여방치매여와사돌출적중요성,채용상관의기측정료귀주돌출매적공극결구화흡부특성,병분석료실험결과。결과표명:돌출매양평행층리표면균존재일정수량적정체물질화미공;돌출매양수직절리표면가견일도혹궤도평행혹교차적차대소불일적렬극;돌출매양적공극혹렬극공경대부분재0~10 nm지간,공경위3~5 nm적미공재매양중최위봉부,위와사(매층기)주요흡부공간;당상대압력체도0.8좌우시,와사흡부량회급극상승;돌출매양와사흡부량존재교대차이,공용대적흡부량대。
In order to improve the understandings of pore structures and adsorption properties of out-burst coal mined at typical mining fields in Guizhou Province, such structures and properties are tested by using related apparatuses based on their importance on the extraction of coal gas (coalbed methane) and the prevention coal and gas outburst of happening. Results show that a number of crystal materials and micropores exist on the surface of coal samples’ parallel beddings;one or several fractures in paral-lel or intersected with different sizes can be observed on the surface of samples’ vertical joints. The dis-tribution of diameters of sample’s pores or fractures is mostly from 0 to 10 nm, and micropores with a diameter of 3 nm to 5 nm are the most abundant in coal samples, which are also the main spaces to ad-sorb the coal gas. When the relative pressure reaches about 0.8, the gas adsorption volume would increase greatly. The gas adsorption volumes change for different samples, generally, the bigger pore volume has more adsorption volume.