中国资源综合利用
中國資源綜閤利用
중국자원종합이용
CHINA RESOURCES COMPREHENSIVE UTILIZATION
2013年
6期
19-21
,共3页
张晓东%冷士良%刘兵%刘晓静%李宗磊
張曉東%冷士良%劉兵%劉曉靜%李宗磊
장효동%랭사량%류병%류효정%리종뢰
废干电池%钛白废硫酸%锰锌铁氧体
廢榦電池%鈦白廢硫痠%錳鋅鐵氧體
폐간전지%태백폐류산%맹자철양체
waste dry battery%titanium waste sulfuric acid%Mn-Zn ferrite
我国每年报废上百万吨的废干电池,钛白工业也会产生大量的废硫酸,这不仅浪费了资源,还严重污染了环境。根据废干电池和钛白废硫酸的特点,本工艺研究用钛白废硫酸浸出废干电池,通过硫化、氧化加热、置换、水解、氟化等净化除杂后,采用共沉淀法制取锰锌铁氧体,产品初始磁导率达8000以上,杂质质量分数小于10-4。该工艺采取以废治废,废物中的主要成分不需相互分离即可制取高附加值的锰锌铁氧体,少量的杂质元素可通过净化脱除并进行处置。
我國每年報廢上百萬噸的廢榦電池,鈦白工業也會產生大量的廢硫痠,這不僅浪費瞭資源,還嚴重汙染瞭環境。根據廢榦電池和鈦白廢硫痠的特點,本工藝研究用鈦白廢硫痠浸齣廢榦電池,通過硫化、氧化加熱、置換、水解、氟化等淨化除雜後,採用共沉澱法製取錳鋅鐵氧體,產品初始磁導率達8000以上,雜質質量分數小于10-4。該工藝採取以廢治廢,廢物中的主要成分不需相互分離即可製取高附加值的錳鋅鐵氧體,少量的雜質元素可通過淨化脫除併進行處置。
아국매년보폐상백만둔적폐간전지,태백공업야회산생대량적폐류산,저불부낭비료자원,환엄중오염료배경。근거폐간전지화태백폐류산적특점,본공예연구용태백폐류산침출폐간전지,통과류화、양화가열、치환、수해、불화등정화제잡후,채용공침정법제취맹자철양체,산품초시자도솔체8000이상,잡질질량분수소우10-4。해공예채취이폐치폐,폐물중적주요성분불수상호분리즉가제취고부가치적맹자철양체,소량적잡질원소가통과정화탈제병진행처치。
Every year millions of tons of waste dry battery are scrapped in our country, and large amount of waste sulfuric acid from titania industry is produced, which not only wastes a lot of resources, but also seriously pollutes the environment. According to the characteristics of waste dry battery and waste sulfuric acid from titania industry, waste dry batteries are soaked in waste sulfuric acid, and then the mixture are purified through process of vulcanization, oxidation heating, substitution, hydrolysis and fluoridization, at last the manganese zinc ferrite is prepare by coprecipitation method. The result of test shows that its μi is more than 8 000 and the mess fraction of impurity is less than 10-4. This process treats waste using waste. The main ingredients of waste do not need to separate, and higher-value manganese zinc ferrite can be prepared. Additionally, a small amount of impurity element can be removed and disposed through purification.