湖北大学学报（自然科学版）
湖北大學學報（自然科學版）
호북대학학보（자연과학판）
2013年
2期
201-204
,共4页
C9馏分%石油树脂%热聚合%收率%色度
C9餾分%石油樹脂%熱聚閤%收率%色度
C9류분%석유수지%열취합%수솔%색도
C9 fraction%petroleum resin%thermal polymerization%yield%chroma
以乙烯裂解副产C9馏分为原料，采用热聚合反应C9制备石油树脂．探讨了反应时间、反应温度和反应压力对石油树脂收率、色度的影响．树脂的收率随着反应时间的延长和反应温度的升高而增大，当反应温度超过240℃，反应时间超过8 h后，石油树脂的收率趋于稳定；随着反应时间的延长，树脂的软化点逐渐降低，树脂的色度逐渐增大．综合分析得适宜的C9石油树脂制备工艺条件为：反应时间8 h ，反应温度230℃，反应压力0．6 MPa ．
以乙烯裂解副產C9餾分為原料，採用熱聚閤反應C9製備石油樹脂．探討瞭反應時間、反應溫度和反應壓力對石油樹脂收率、色度的影響．樹脂的收率隨著反應時間的延長和反應溫度的升高而增大，噹反應溫度超過240℃，反應時間超過8 h後，石油樹脂的收率趨于穩定；隨著反應時間的延長，樹脂的軟化點逐漸降低，樹脂的色度逐漸增大．綜閤分析得適宜的C9石油樹脂製備工藝條件為：反應時間8 h ，反應溫度230℃，反應壓力0．6 MPa ．
이을희렬해부산C9류분위원료，채용열취합반응C9제비석유수지．탐토료반응시간、반응온도화반응압력대석유수지수솔、색도적영향．수지적수솔수착반응시간적연장화반응온도적승고이증대，당반응온도초과240℃，반응시간초과8 h후，석유수지적수솔추우은정；수착반응시간적연장，수지적연화점축점강저，수지적색도축점증대．종합분석득괄의적C9석유수지제비공예조건위：반응시간8 h ，반응온도230℃，반응압력0．6 MPa ．
C9 petroleum resin was prepared by thermal polymerization from C 9 distillate fractions of ethylene pyrolysis in this paper .Influence of the reaction condition (reaction time ,temperature and pressure) on the yield and chroma ,petroleum resin bromine value and diene value of solvent oil was investigated .The cracking crude C9 fractions were analyzed by infrared spectrum (IR) .The softening point and chroma of petroleum resin was also measured with standard test .The experimental results showed that the composition of C 9 distillate fractions was very complex , and the main active ingredients were styrene and its homologues .The petroleum resin yield increased with the increase of reaction time or temperature ,when the reaction temperature was above 240 ℃or the time was beyond 8 h ,the yield was tend to stabilize gradually .With the extension of reaction time ,the bromine value , diene value of solvent oil and the softening point of resin declined gradually while the chroma of resin increased . The optimal reaction conditions were determined as follows : the reactive time and temperature were 230 ℃ and 8h respectively ,the reaction pressure was 0 .6 M Pa .
