化学研究
化學研究
화학연구
CHEMICAL RESEARCHES
2013年
4期
384-386
,共3页
陈木子%国永敏%李艺%李宝宗
陳木子%國永敏%李藝%李寶宗
진목자%국영민%리예%리보종
手性两亲小分子%模板%介孔%二氧化硅%纳米空心球%制备
手性兩親小分子%模闆%介孔%二氧化硅%納米空心毬%製備
수성량친소분자%모판%개공%이양화규%납미공심구%제비
chrial amphiphile%template%mesoporous%silica%hollow nanosphere%preparation
以 L-亮氨酸为手性源合成了手性阳离子两亲性小分子化合物 L-18Leu6NEtBr ,用其自组装体作为模板,氢氧化钠为催化剂,经溶胶-凝胶过程制备出介孔二氧化硅纳米空心球;分析了介孔二氧化硅纳米空心球的尺寸和孔径.结果表明,所制备的二氧化硅空心球直径约100 nm ;其介孔孔道平行于壳表面,孔径为3.1 nm .
以 L-亮氨痠為手性源閤成瞭手性暘離子兩親性小分子化閤物 L-18Leu6NEtBr ,用其自組裝體作為模闆,氫氧化鈉為催化劑,經溶膠-凝膠過程製備齣介孔二氧化硅納米空心毬;分析瞭介孔二氧化硅納米空心毬的呎吋和孔徑.結果錶明,所製備的二氧化硅空心毬直徑約100 nm ;其介孔孔道平行于殼錶麵,孔徑為3.1 nm .
이 L-량안산위수성원합성료수성양리자량친성소분자화합물 L-18Leu6NEtBr ,용기자조장체작위모판,경양화납위최화제,경용효-응효과정제비출개공이양화규납미공심구;분석료개공이양화규납미공심구적척촌화공경.결과표명,소제비적이양화규공심구직경약100 nm ;기개공공도평행우각표면,공경위3.1 nm .
Silica hollow nanospheres with single-layer mesopores in their shells were prepared through a sol-gel transcription approach via the self-assembly of a chiral low-molecular-weight amphiphile derived from L-leucine as the template and sodium hydroxide as the catalyst .The size and pore diameter of as-synthesized silica hollow nanospheres were analyzed .It was found that as-synthesized silica hollow nanospheres have a diameter of about 100 nm ;their meso-porous channels are parallel to their shell surface ,and the diameter of their pore channels in the shells is about 3 .1 nm .