当代化工
噹代化工
당대화공
CONTEMPORARY CHEMICAL INDUSTRY
2013年
5期
548-550
,共3页
史册%张永利%苏晓银%尚玲玲%刘永民
史冊%張永利%囌曉銀%尚玲玲%劉永民
사책%장영리%소효은%상령령%류영민
Ru系催化剂%有机废水%高级氧化%SEM表征%TG-DTA表征
Ru繫催化劑%有機廢水%高級氧化%SEM錶徵%TG-DTA錶徵
Ru계최화제%유궤폐수%고급양화%SEM표정%TG-DTA표정
Ru-based catalysts%Organic wastewater%Advanced oxidation%SEM%TG-DTA
催化剂的制备采用等量浸渍方法,以三叶草状γ-Al2O3为催化剂载体,Cu、Fe、Ru为催化剂活性组分,La为催化助剂,研制贵金属Ru系复合催化剂。采用催化湿式空气氧化法(CWAO)处理有机废水,对制备的催化剂进行SEM和TG-DTA表征。结果表明:制备的负载型催化剂各活性组分能够很好地分布在载体表面,能够有效提高催化剂活性,制备催化剂时硝酸盐分解大概在230~440℃之间,焙烧温度不宜过高。
催化劑的製備採用等量浸漬方法,以三葉草狀γ-Al2O3為催化劑載體,Cu、Fe、Ru為催化劑活性組分,La為催化助劑,研製貴金屬Ru繫複閤催化劑。採用催化濕式空氣氧化法(CWAO)處理有機廢水,對製備的催化劑進行SEM和TG-DTA錶徵。結果錶明:製備的負載型催化劑各活性組分能夠很好地分佈在載體錶麵,能夠有效提高催化劑活性,製備催化劑時硝痠鹽分解大概在230~440℃之間,焙燒溫度不宜過高。
최화제적제비채용등량침지방법,이삼협초상γ-Al2O3위최화제재체,Cu、Fe、Ru위최화제활성조분,La위최화조제,연제귀금속Ru계복합최화제。채용최화습식공기양화법(CWAO)처리유궤폐수,대제비적최화제진행SEM화TG-DTA표정。결과표명:제비적부재형최화제각활성조분능구흔호지분포재재체표면,능구유효제고최화제활성,제비최화제시초산염분해대개재230~440℃지간,배소온도불의과고。
Noble metal Ru-based catalysts were prepared by the impregnation method with clover shapedγ-Al2O3 as carrier, Cu, Fe and Ru as active components, La as the catalytic additive. Organic wastewater was treated by catalytic wet air oxidation (CWAO). Prepared catalysts were characterized by SEM and TG-DTA. The results show that each of the active components of the supported catalysts prepared in this experiment can be well distributed on the surface of the carrier. It’s able to effectively improve the activity of catalyst;Nitrates can be decomposed in the range of 230~440 ℃ during preparing catalysts, so calcination temperature should not be too high.