含能材料
含能材料
함능재료
ENERGETIC MATERIALS
2013年
6期
717-720
,共4页
李祥志%王伯周%李亚南%李辉%周诚%张叶高%廉鹏
李祥誌%王伯週%李亞南%李輝%週誠%張葉高%廉鵬
리상지%왕백주%리아남%리휘%주성%장협고%렴붕
有机化学%5H-1,2,3三唑并4,5-c呋咱%含能衍生物%表征%合成%热性能
有機化學%5H-1,2,3三唑併4,5-c呋偺%含能衍生物%錶徵%閤成%熱性能
유궤화학%5H-1,2,3삼서병4,5-c부찰%함능연생물%표정%합성%열성능
organic chemistry%5H-[1,2,3]triazolo[4,5-c][1,2,5]oxdiazole%energetic derivatives%characterization%synthesis%thermal property
以呋咱并[3,4-e]-1,2,3,4-四嗪-4,6-二氧化物(FTDO)为原料,经水解反应合成了新型富氮含能材料5H-[1,2,3]三唑并[4,5-c]呋咱(2),然后与氨气、水合肼、脒基脲盐酸盐、三氨基胍硝酸盐反应合成了[1,2,3]三唑并[4,5-c]呋咱铵盐(3)、[1,2,3]三唑并[4,5-c]呋咱肼盐(4)、[1,2,3]三唑并[4,5-c]呋咱脒基脲盐(5)和[1,2,3]三唑并[4,5-c]呋咱三氨基胍盐(6)4种新的含能衍生物,并采用红外光谱、核磁共振光谱、元素分析等进行了结构表征;探讨了水解反应的机理和条件,确定最佳条件为:80℃下反应5 h,收率为76.92%;采用DSC热分析手段研究了化合物2、4、5和6的热性能,其初始分解峰温分别为173.23,144.82,172.81,164.94℃。
以呋偺併[3,4-e]-1,2,3,4-四嗪-4,6-二氧化物(FTDO)為原料,經水解反應閤成瞭新型富氮含能材料5H-[1,2,3]三唑併[4,5-c]呋偺(2),然後與氨氣、水閤肼、脒基脲鹽痠鹽、三氨基胍硝痠鹽反應閤成瞭[1,2,3]三唑併[4,5-c]呋偺銨鹽(3)、[1,2,3]三唑併[4,5-c]呋偺肼鹽(4)、[1,2,3]三唑併[4,5-c]呋偺脒基脲鹽(5)和[1,2,3]三唑併[4,5-c]呋偺三氨基胍鹽(6)4種新的含能衍生物,併採用紅外光譜、覈磁共振光譜、元素分析等進行瞭結構錶徵;探討瞭水解反應的機理和條件,確定最佳條件為:80℃下反應5 h,收率為76.92%;採用DSC熱分析手段研究瞭化閤物2、4、5和6的熱性能,其初始分解峰溫分彆為173.23,144.82,172.81,164.94℃。
이부찰병[3,4-e]-1,2,3,4-사진-4,6-이양화물(FTDO)위원료,경수해반응합성료신형부담함능재료5H-[1,2,3]삼서병[4,5-c]부찰(2),연후여안기、수합정、미기뇨염산염、삼안기고초산염반응합성료[1,2,3]삼서병[4,5-c]부찰안염(3)、[1,2,3]삼서병[4,5-c]부찰정염(4)、[1,2,3]삼서병[4,5-c]부찰미기뇨염(5)화[1,2,3]삼서병[4,5-c]부찰삼안기고염(6)4충신적함능연생물,병채용홍외광보、핵자공진광보、원소분석등진행료결구표정;탐토료수해반응적궤리화조건,학정최가조건위:80℃하반응5 h,수솔위76.92%;채용DSC열분석수단연구료화합물2、4、5화6적열성능,기초시분해봉온분별위173.23,144.82,172.81,164.94℃。
A novel nitrogen-rich energetic material 5H-[1,2,3]triazolo[4,5-c][1,2,5]oxdiazole(2) was prepared via hydrolytic reac-tion using [1,2,5]oxadiazole [3,4-e][1,2,3,4]tetrazine 4,6-di-N-oxide(FTDO) as raw material.Four new energetic derivatives, am-monium [1,2,3]triazolo [4,5-c][1,2,5]oxdiazole(3), hydrazinium [1,2,3]triazolo[4,5-c][1,2,5]oxdiazole(4), guanylureaium [1,2,3]triazolo[4,5-c][1,2,5]oxdiazole(5) and triaminoguanidinium [1,2,3] triazolo[4,5-c][1,2,5]oxdiazole(6) were designed and synthesized via reactions of compound 2 with ammonia gas, hydrazine hydrate, amidinothiourea hydrochloride and triaminogunidine nitrate, respectively.Their structures were characterized by IR, NMR and elemental analysis.The mechanism and conditions of hydrolytic reaction were analyzed.The optimal reaction conditions were determined as:the reaction time 5 h and reaction tempera-ture 80 ℃with a yield of 76.92%.The thermal properties of compounds, 2,4,5 and 6, were analyzed by DSC.Results show that their peak temperatures of initial decomposition reaction are 173.23, 144.82, 172.81, 164.94 ℃, respectively.