哈尔滨工程大学学报
哈爾濱工程大學學報
합이빈공정대학학보
JOURNAL OF HARBIN ENGINEERING UNIVERSITY
2013年
11期
1465-1470
,共6页
李成涛%宋利君%任爱%刘飞华%李岩%李晓刚%程学群
李成濤%宋利君%任愛%劉飛華%李巖%李曉剛%程學群
리성도%송리군%임애%류비화%리암%리효강%정학군
690合金%应力腐蚀%一回路%核电%腐蚀
690閤金%應力腐蝕%一迴路%覈電%腐蝕
690합금%응력부식%일회로%핵전%부식
alloy 690%stress corrosion%primary water%nuclear power plant%corrosion product
针对690合金应力腐蚀问题,在核电一回路模拟环境中,采用恒载荷和慢应变速率拉伸实验方法,研究了690合金的应力腐蚀开裂行为,并通过扫描电镜、能谱分析和X射线衍射方法对表面形貌、截面形貌和断口形貌进行观察与分析。扫描电镜结果表明,样品表面被颗粒状腐蚀产物所覆盖,成分主要为Fe、Ni、Cr的尖晶石氧化物;表面状态对表面腐蚀形貌影响较大;690合金恒载荷试样经历2100 h腐蚀试验后未发生应力腐蚀开裂;拉伸试样表现出低的应力腐蚀敏感性,断口形貌为韧性断口和脆性断口的混合模式。
針對690閤金應力腐蝕問題,在覈電一迴路模擬環境中,採用恆載荷和慢應變速率拉伸實驗方法,研究瞭690閤金的應力腐蝕開裂行為,併通過掃描電鏡、能譜分析和X射線衍射方法對錶麵形貌、截麵形貌和斷口形貌進行觀察與分析。掃描電鏡結果錶明,樣品錶麵被顆粒狀腐蝕產物所覆蓋,成分主要為Fe、Ni、Cr的尖晶石氧化物;錶麵狀態對錶麵腐蝕形貌影響較大;690閤金恆載荷試樣經歷2100 h腐蝕試驗後未髮生應力腐蝕開裂;拉伸試樣錶現齣低的應力腐蝕敏感性,斷口形貌為韌性斷口和脆性斷口的混閤模式。
침대690합금응력부식문제,재핵전일회로모의배경중,채용항재하화만응변속솔랍신실험방법,연구료690합금적응력부식개렬행위,병통과소묘전경、능보분석화X사선연사방법대표면형모、절면형모화단구형모진행관찰여분석。소묘전경결과표명,양품표면피과립상부식산물소복개,성분주요위Fe、Ni、Cr적첨정석양화물;표면상태대표면부식형모영향교대;690합금항재하시양경력2100 h부식시험후미발생응력부식개렬;랍신시양표현출저적응력부식민감성,단구형모위인성단구화취성단구적혼합모식。
The stress corrosion cracking ( SCC) behavior of alloy 690 in primary water was investigated using the static load test and slow strain rate test. The surface, cross section and fracture morphology were analyzed by using scanning electron microscopy ( SEM) , energy dispersive spectrometer ( EDS) and X-ray diffraction. The results of the SEM showed that the surface is uniformly covered by corrosive oxide particles. The corrosion product mainly consists of spinel oxides of Fe, Ni and Cr. The surface condition has great effect on the corro-sion morphology. After a 2100 hours corrosion test in primary water, no significant SCC was observed in the static load specimens of alloy 690. The slow strain specimens have low susceptibility to SCC in primary water. The fracture morphology was the mixed mode of the ductile fracture and the brittle fracture.