CAJ | 학술논문

首先借助种子乳液聚合手段，以苯乙烯、二乙烯苯为混合单体，在致孔剂存在下制备出壳具有微通道的聚苯乙烯核壳结构模板微球。利用该模板，通过毛细管力对导电聚合物单体进行充分吸附，利用溶液聚合制备了表面包覆均匀的有机导电聚合物(聚吡咯、聚苯胺)包覆聚苯乙烯复合微球，导电率达到5.5×10-5 S/cm左右。并成功利用水溶性很差、且在水体系中难以聚合的噻吩单体，通过相转移催化实现了对模板微球的包覆，得到表面形貌独特的聚噻吩包覆聚苯乙烯复合微球。
수선차조충자유액취합수단，이분을희、이을희분위혼합단체，재치공제존재하제비출각구유미통도적취분을희핵각결구모판미구。이용해모판，통과모세관력대도전취합물단체진행충분흡부，이용용액취합제비료표면포복균균적유궤도전취합물(취필각、취분알)포복취분을희복합미구，도전솔체도5.5×10-5 S/cm좌우。병성공이용수용성흔차、차재수체계중난이취합적새분단체，통과상전이최화실현료대모판미구적포복，득도표면형모독특적취새분포복취분을희복합미구。
In this paper,polystyrene (PS)core-shell template particles with microchannels in shell were pre-pared through seed-polymerization by using mixed monomers of styrene (St)and divinyl benzene (DVB)with PS seeds emulsion firstly.Using the template particles,organic conductive polymers(OCPs)-coated PS com-posite particles were synthesized under capillary force through solution polymerization of polypyrrole (PPy)and polyaniline (PANI),and the conductivity of the particles was about 5.5×10-5S/cm.Furthermore,the nano-composite particle of PS/PTh was synthesized using thiophene(Th)chemical oxidative polymerization through phase transfer catalysis method.The overlayers of the core-shell PS/PTh composite spheres have diverse sur-face morphology.