功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
22期
3301-3304
,共4页
张振兴%张海军%廖梦舟%周华%谢二庆%潘孝军
張振興%張海軍%廖夢舟%週華%謝二慶%潘孝軍
장진흥%장해군%료몽주%주화%사이경%반효군
ZnO 薄膜%K-N 共掺杂%光学带隙%光致发光谱%溶胶-凝胶法
ZnO 薄膜%K-N 共摻雜%光學帶隙%光緻髮光譜%溶膠-凝膠法
ZnO 박막%K-N 공참잡%광학대극%광치발광보%용효-응효법
ZnO film%K-N co-doping%optical band-gap%photoluminescence%sol-gel method
采用溶胶-凝胶法在 Si(100)衬底上生长了K与N共掺的ZnO 薄膜,并用 X射线衍射仪、扫描电子显微镜、荧光分光光度计、紫外-可见分光光度计对ZnO 薄膜样品的结构和光学特性进行了研究。结果表明,溶胶-凝胶法制备的 ZnO 薄膜为六方纤锌矿结构。随着K掺杂浓度的增大,薄膜的结晶性变好,组成薄膜的颗粒变大,并表现出c 轴择优生长特性,同时掺杂导致的氧空位缺陷也在增加,使得绿光发射增强,薄膜的光学带隙先增后减。
採用溶膠-凝膠法在 Si(100)襯底上生長瞭K與N共摻的ZnO 薄膜,併用 X射線衍射儀、掃描電子顯微鏡、熒光分光光度計、紫外-可見分光光度計對ZnO 薄膜樣品的結構和光學特性進行瞭研究。結果錶明,溶膠-凝膠法製備的 ZnO 薄膜為六方纖鋅礦結構。隨著K摻雜濃度的增大,薄膜的結晶性變好,組成薄膜的顆粒變大,併錶現齣c 軸擇優生長特性,同時摻雜導緻的氧空位缺陷也在增加,使得綠光髮射增彊,薄膜的光學帶隙先增後減。
채용용효-응효법재 Si(100)츤저상생장료K여N공참적ZnO 박막,병용 X사선연사의、소묘전자현미경、형광분광광도계、자외-가견분광광도계대ZnO 박막양품적결구화광학특성진행료연구。결과표명,용효-응효법제비적 ZnO 박막위륙방섬자광결구。수착K참잡농도적증대,박막적결정성변호,조성박막적과립변대,병표현출c 축택우생장특성,동시참잡도치적양공위결함야재증가,사득록광발사증강,박막적광학대극선증후감。
The K-N co-doped ZnO films were prepared on Si(100)substrates by sol-gel method.The structure and the optical properties of the ZnO films were investigated by X-ray diffraction,scanning electron microsco-py,photoluminescence and ultraviolet and visible spectrophotometer.The results show that the films exhibit a hexagonal structure.As the concentration of potassium increases,the crystallinity of the films was improved and the grain size increases,showing a preferential growth along c axis.Meanwhile,the increased concentration of K-N doping results in increased oxygen vacancies,enhanced green photoluminescence,and the optical band-gap that increases first and then decreases.