功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
22期
3291-3295
,共5页
吴勃%周明%李保家%王云龙%蔡兰
吳勃%週明%李保傢%王雲龍%蔡蘭
오발%주명%리보가%왕운룡%채란
超快光学%飞秒激光%表面微结构%血液相容性%医用不锈钢
超快光學%飛秒激光%錶麵微結構%血液相容性%醫用不鏽鋼
초쾌광학%비초격광%표면미결구%혈액상용성%의용불수강
ultrafast optics%femtosecond laser%surface microstructure%blood compatibility%medical stainless steel
利用飞秒激光在316L不锈钢表面诱导制备血液相容性微结构,并从微结构的润湿性角度分析血液相容性改善的机理。随着激光能量密度的增加,在样品表面分别制备了单一的亚微米级典型激光诱导周期性波纹(LIPSS),以及两种双尺度结构,即覆盖了LIPSS的微米级波纹结构和锥状钉结构。硅烷化后的微结构样品表观接触角都超过150°,达到了超疏水性能要求,并且随着所采用激光能量密度的增强而增大,尤其是锥状钉双尺度结构的接触角达到了163.8°。采用了3种常规评价方法对微结构表面的血液相容性进行了评价,结果表明微结构表面的血液相容性显著优于光滑表面,且随着表面的表观接触角的增大而改善。
利用飛秒激光在316L不鏽鋼錶麵誘導製備血液相容性微結構,併從微結構的潤濕性角度分析血液相容性改善的機理。隨著激光能量密度的增加,在樣品錶麵分彆製備瞭單一的亞微米級典型激光誘導週期性波紋(LIPSS),以及兩種雙呎度結構,即覆蓋瞭LIPSS的微米級波紋結構和錐狀釘結構。硅烷化後的微結構樣品錶觀接觸角都超過150°,達到瞭超疏水性能要求,併且隨著所採用激光能量密度的增彊而增大,尤其是錐狀釘雙呎度結構的接觸角達到瞭163.8°。採用瞭3種常規評價方法對微結構錶麵的血液相容性進行瞭評價,結果錶明微結構錶麵的血液相容性顯著優于光滑錶麵,且隨著錶麵的錶觀接觸角的增大而改善。
이용비초격광재316L불수강표면유도제비혈액상용성미결구,병종미결구적윤습성각도분석혈액상용성개선적궤리。수착격광능량밀도적증가,재양품표면분별제비료단일적아미미급전형격광유도주기성파문(LIPSS),이급량충쌍척도결구,즉복개료LIPSS적미미급파문결구화추상정결구。규완화후적미결구양품표관접촉각도초과150°,체도료초소수성능요구,병차수착소채용격광능량밀도적증강이증대,우기시추상정쌍척도결구적접촉각체도료163.8°。채용료3충상규평개방법대미결구표면적혈액상용성진행료평개,결과표명미결구표면적혈액상용성현저우우광활표면,차수착표면적표관접촉각적증대이개선。
Microstructures with a good blood compatibility on the surface of stainless steel were prepared by using a femtosecond laser.The mechanism of the blood compatibility improvement was analyzed from the wet-tability of the microstructure perspective.With laser fluence increasing,we fabricated single typical laser-in-duced periodic surface structures (LIPSS)on the submicron scale and double-scale structure:periodic ripples and periodic cone-shaped spikes on the micron scale,both covered with LIPSS.After silanized,the apparent contact angles of these microstructures become larger than 150°,which meets the superhydrophobic perform-ance requirements.With the laser fluence increasing,the apparent contact angles increase,and especially the contact angle of the cone-shaped double-scale structure reaches as high as 163.8°.The blood compatibility of the microstructures was evaluated with 3 conventional evaluation methods.The results show that the blood com-patibility of the microstructures was significantly better than that of the polished surface,and that with the con-tact angles of the surface increasing,the blood compatibility can be further improved.