含能材料
含能材料
함능재료
ENERGETIC MATERIALS
2013年
4期
506-511
,共6页
林聪妹%刘世俊%涂小珍%黄忠%李玉斌%潘丽萍%张建虎
林聰妹%劉世俊%塗小珍%黃忠%李玉斌%潘麗萍%張建虎
림총매%류세준%도소진%황충%리옥빈%반려평%장건호
应用化学%TATB%高聚物粘结炸药%增强剂%蠕变性能%时温等效
應用化學%TATB%高聚物粘結炸藥%增彊劑%蠕變性能%時溫等效
응용화학%TATB%고취물점결작약%증강제%연변성능%시온등효
applied chemistry%TATB%polymer bonded explosive%reinforcing agent%creep properties%time-temperature superpo-sition
为探讨粘结剂组成对 TATB基高聚物粘结炸药( PBX)蠕变性能的影响,用电子万能试验机和动态力学分析仪分别研究了TATB基PBX及其改性配方的拉伸、压缩和三点弯曲蠕变行为。结果表明,加入高玻璃化转变温度和高力学强度的增强剂苯乙烯共聚物可改善 TATB 基 PBX 的抗蠕变性能。改性配方的蠕变应变降低,蠕变破坏时间延长。由50℃/3 MPa 下拉伸蠕变、70℃/10 MPa下压缩蠕变以及70℃/6 MPa下三点弯曲蠕变试验所得原配方的破坏时间分别为14,12.7,12 min,而同样条件下,改性配方未发生蠕变破坏。根据时温等效原理,获得 TATB基 PBX及其改性配方在参考温度60℃下的蠕变柔量主曲线。与原配方相比,TATB基 PBX改性配方的蠕变柔量主曲线向下偏移,抗蠕变性能提高。
為探討粘結劑組成對 TATB基高聚物粘結炸藥( PBX)蠕變性能的影響,用電子萬能試驗機和動態力學分析儀分彆研究瞭TATB基PBX及其改性配方的拉伸、壓縮和三點彎麯蠕變行為。結果錶明,加入高玻璃化轉變溫度和高力學彊度的增彊劑苯乙烯共聚物可改善 TATB 基 PBX 的抗蠕變性能。改性配方的蠕變應變降低,蠕變破壞時間延長。由50℃/3 MPa 下拉伸蠕變、70℃/10 MPa下壓縮蠕變以及70℃/6 MPa下三點彎麯蠕變試驗所得原配方的破壞時間分彆為14,12.7,12 min,而同樣條件下,改性配方未髮生蠕變破壞。根據時溫等效原理,穫得 TATB基 PBX及其改性配方在參攷溫度60℃下的蠕變柔量主麯線。與原配方相比,TATB基 PBX改性配方的蠕變柔量主麯線嚮下偏移,抗蠕變性能提高。
위탐토점결제조성대 TATB기고취물점결작약( PBX)연변성능적영향,용전자만능시험궤화동태역학분석의분별연구료TATB기PBX급기개성배방적랍신、압축화삼점만곡연변행위。결과표명,가입고파리화전변온도화고역학강도적증강제분을희공취물가개선 TATB 기 PBX 적항연변성능。개성배방적연변응변강저,연변파배시간연장。유50℃/3 MPa 하랍신연변、70℃/10 MPa하압축연변이급70℃/6 MPa하삼점만곡연변시험소득원배방적파배시간분별위14,12.7,12 min,이동양조건하,개성배방미발생연변파배。근거시온등효원리,획득 TATB기 PBX급기개성배방재삼고온도60℃하적연변유량주곡선。여원배방상비,TATB기 PBX개성배방적연변유량주곡선향하편이,항연변성능제고。
In order to investigate the effects of binder component on the creep properties of TATB-based polymer bonded explosive ( PBX),tensile creep properties,compressive creep properties and three-point bending creep behavior of TATB-based PBX were studied by electronic universal testing machine and dynamic mechanical analyzer, respectively. Results showed that creep resistance performance was improved by the addition of reinforcing agent( styrene copolymer)with high glass transition tempera-ture and high mechanical strength. The creep strain of modified formulation was decreased,creep failure time prolonged. The creep damage time of original formulation obtained by 50 ℃/3 MPa tensile creep,70 ℃/10 MPa compressive creep and 70 ℃/6 MPa three-point bending creep tests were 14,12. 7,12 min,respectively. However,modified formulation did not rup-ture under the same conditions. Based on time-temperature superposition principle,the master curves of TATB-based PBX and its modified formulation were obtained at reference temperature of 60 ℃. Compared with original formulation,the creep compliance master curves of modified formulation shifted downward and the creep resistance performance was enhanced.