含能材料
含能材料
함능재료
ENERGETIC MATERIALS
2013年
4期
495-499
,共5页
肖玮%李亮亮%王江宁%苏健军%王世英%董树南%屈可朋
肖瑋%李亮亮%王江寧%囌健軍%王世英%董樹南%屈可朋
초위%리량량%왕강저%소건군%왕세영%동수남%굴가붕
物理化学%改性双基推进剂%力学性能%3,4-二硝基呋咱基氧化呋咱(DNTF)%RDX
物理化學%改性雙基推進劑%力學性能%3,4-二硝基呋偺基氧化呋偺(DNTF)%RDX
물이화학%개성쌍기추진제%역학성능%3,4-이초기부찰기양화부찰(DNTF)%RDX
physical chemistry%composite modified double-base propellant%mechanical performance%3,4-bisnitrofurazanfuroxan (DNTF)%1,3,5-trinitrohexahydrotriazine(RDX)
用单轴抗拉实验、动态力学分析仪和简支梁抗冲实验研究了不同3,4-二硝基呋咱基氧化呋咱( DNTF)/ RDX 配比对DNTF/RDX改性双基( CMDB)推进剂( DNTF/RDX-CMDB,DFR推进剂)力学性能的影响。获得了-40℃下 DFR 推进剂的抗拉强度(σm )、断裂延伸率(εm )及抗冲强度( aK )。根据“时间-温度”等效原理的 WLF方程获得了 DFR推进剂β松弛阶段的动态特征量黏弹系数(Cg1)。分析了组分含量对各力学性能的影响和σm、εm 的变化规律。结果表明:低温下的σm、εm 和 aK 均与增塑剂含量间存在相关性。增塑剂含量减小,粘弹系数增加,NC分子侧基的“自由体积”下降,导致抗拉强度、断裂延伸率等力学性能降低。
用單軸抗拉實驗、動態力學分析儀和簡支樑抗遲實驗研究瞭不同3,4-二硝基呋偺基氧化呋偺( DNTF)/ RDX 配比對DNTF/RDX改性雙基( CMDB)推進劑( DNTF/RDX-CMDB,DFR推進劑)力學性能的影響。穫得瞭-40℃下 DFR 推進劑的抗拉彊度(σm )、斷裂延伸率(εm )及抗遲彊度( aK )。根據“時間-溫度”等效原理的 WLF方程穫得瞭 DFR推進劑β鬆弛階段的動態特徵量黏彈繫數(Cg1)。分析瞭組分含量對各力學性能的影響和σm、εm 的變化規律。結果錶明:低溫下的σm、εm 和 aK 均與增塑劑含量間存在相關性。增塑劑含量減小,粘彈繫數增加,NC分子側基的“自由體積”下降,導緻抗拉彊度、斷裂延伸率等力學性能降低。
용단축항랍실험、동태역학분석의화간지량항충실험연구료불동3,4-이초기부찰기양화부찰( DNTF)/ RDX 배비대DNTF/RDX개성쌍기( CMDB)추진제( DNTF/RDX-CMDB,DFR추진제)역학성능적영향。획득료-40℃하 DFR 추진제적항랍강도(σm )、단렬연신솔(εm )급항충강도( aK )。근거“시간-온도”등효원리적 WLF방정획득료 DFR추진제β송이계단적동태특정량점탄계수(Cg1)。분석료조분함량대각역학성능적영향화σm、εm 적변화규률。결과표명:저온하적σm、εm 화 aK 균여증소제함량간존재상관성。증소제함량감소,점탄계수증가,NC분자측기적“자유체적”하강,도치항랍강도、단렬연신솔등역학성능강저。
Influence of different ratios of 1,3,5-trinitrohexahydrotriazine(RDX)to 3,4-bisnitrofurazan-furoxan(DNTF)on the me-chanical properties of DNTF/RDX composite modified double-base( CMDB)propellant( DNTF/RDX-CMDB,DFR propellant) was studied by uniaxial tensile test,charpy impact test and dynamic mechanical analyzer. The tensile strength(σm ),elongation at the maximum stress(εm )and impact strength( aK )of DFR propellant at -40 ℃ were obtained. The dynamical characteristics (viscoelastic coefficients Cg1)of β-relaxation was acquired by WLF equation according to the“Time-Temperature”equivalence principle. The effect of plasticizer content on the various mechanical properties and change rule of σm and εm were analyzed, showing that a good correlation between σm ,εm ,aK at low temperature and plasticizer content. The plasticizer content reducing, Cg1 increasing,“free volume of side group of NC molecule”decreasing make the mechanical performances(σm and εm )worsen.