有色金属科学与工程
有色金屬科學與工程
유색금속과학여공정
JIANGXI NONFERROUS METALS
2013年
4期
47-50
,共4页
CuO%纳米线%气敏性能%热氧化
CuO%納米線%氣敏性能%熱氧化
CuO%납미선%기민성능%열양화
CuO%nanowires%gas sensing%thermal oxidation
传统金属氧化物气敏材料因其灵敏度低、选择性差、工作温度高等缺点已很难满足高性能气敏元件的要求,而纳米气敏材料具有高的比表面积,可显著改善材料的气敏特性.文中采用简单的电热板在330~430℃、空气气氛下、一步法成功制备出了具有良好单斜晶体结构的CuO纳米线,平均直径为20~30 nm,长度可达1~5μm;CuO纳米线气敏元件在100×10-6乙醇气氛中的最佳工作温度约为260℃,其灵敏度分别为1.36和1.64,恢复和响应时间均小于5 s.
傳統金屬氧化物氣敏材料因其靈敏度低、選擇性差、工作溫度高等缺點已很難滿足高性能氣敏元件的要求,而納米氣敏材料具有高的比錶麵積,可顯著改善材料的氣敏特性.文中採用簡單的電熱闆在330~430℃、空氣氣氛下、一步法成功製備齣瞭具有良好單斜晶體結構的CuO納米線,平均直徑為20~30 nm,長度可達1~5μm;CuO納米線氣敏元件在100×10-6乙醇氣氛中的最佳工作溫度約為260℃,其靈敏度分彆為1.36和1.64,恢複和響應時間均小于5 s.
전통금속양화물기민재료인기령민도저、선택성차、공작온도고등결점이흔난만족고성능기민원건적요구,이납미기민재료구유고적비표면적,가현저개선재료적기민특성.문중채용간단적전열판재330~430℃、공기기분하、일보법성공제비출료구유량호단사정체결구적CuO납미선,평균직경위20~30 nm,장도가체1~5μm;CuO납미선기민원건재100×10-6을순기분중적최가공작온도약위260℃,기령민도분별위1.36화1.64,회복화향응시간균소우5 s.
It is difficult for the traditional metal oxide gas-sensing materials to meet the high performance gas-sensing devices requirement due to the low sensitivity, poor selectivity and high working temperature. Nano-sized material with a high specific surface area can improve gas-sensing properties notably. Herein, sin-gle crystalline CuO nanowires with an average 20~30 nm in diameters, 1~5 μm in length are obtained by ther-mal oxidation copper powders at 330 and 430 ° C in air condition. The optimum working temperature of the sensors based on as-prepared CuO nanowires is about 260 °C in 100 ppm ethanol, with the sensitivity of 1.36 and 1.64 respectively. Both the response and recovery time are less than 5 s.