中国有色金属学报(英文版)
中國有色金屬學報(英文版)
중국유색금속학보(영문판)
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
2013年
6期
1804-1814
,共11页
刘云国%廖婷%贺仲兵%李婷婷%王慧%胡新将%郭一明%何缘
劉雲國%廖婷%賀仲兵%李婷婷%王慧%鬍新將%郭一明%何緣
류운국%료정%하중병%리정정%왕혜%호신장%곽일명%하연
生物吸附%枯草芽孢杆菌%固定化枯草芽孢杆菌%Cu(II)%吸附平衡%动力学
生物吸附%枯草芽孢桿菌%固定化枯草芽孢桿菌%Cu(II)%吸附平衡%動力學
생물흡부%고초아포간균%고정화고초아포간균%Cu(II)%흡부평형%동역학
biosorption%Bacillus subtilis%Bacillus subtilis immobilized into chitosan beads (BICB)%Cu(II)%isotherms%kinetic
研究了壳聚糖固定化枯草芽孢杆菌吸附铜离子的性能,分析了 pH、吸附剂投加量、温度、铜离子初始浓度和时间对铜离子吸附的影响。结果表明, pH对铜离子的吸附有较大的影响。此外,固定化枯草芽孢杆菌吸附剂比空白吸附剂具有更强的吸附性能。整个吸附过程符合朗缪尔吸附模型(R2=0.994),最大吸附量为100.70 mg/L。动力学模型拟合结果表明,实验符合准二级动力学模型,线性相关指数大于0.999。吸附剂能在0.1 mol/L NaOH溶液中被成功解吸。
研究瞭殼聚糖固定化枯草芽孢桿菌吸附銅離子的性能,分析瞭 pH、吸附劑投加量、溫度、銅離子初始濃度和時間對銅離子吸附的影響。結果錶明, pH對銅離子的吸附有較大的影響。此外,固定化枯草芽孢桿菌吸附劑比空白吸附劑具有更彊的吸附性能。整箇吸附過程符閤朗繆爾吸附模型(R2=0.994),最大吸附量為100.70 mg/L。動力學模型擬閤結果錶明,實驗符閤準二級動力學模型,線性相關指數大于0.999。吸附劑能在0.1 mol/L NaOH溶液中被成功解吸。
연구료각취당고정화고초아포간균흡부동리자적성능,분석료 pH、흡부제투가량、온도、동리자초시농도화시간대동리자흡부적영향。결과표명, pH대동리자적흡부유교대적영향。차외,고정화고초아포간균흡부제비공백흡부제구유경강적흡부성능。정개흡부과정부합랑무이흡부모형(R2=0.994),최대흡부량위100.70 mg/L。동역학모형의합결과표명,실험부합준이급동역학모형,선성상관지수대우0.999。흡부제능재0.1 mol/L NaOH용액중피성공해흡。
The ability of Bacillus subtilis immobilized into chitosan beads (BICB) to remove Cu(II) from aqueous solution was studied. The effects of pH, biosorbent dosage, temperature, initial Cu(II) concentration and contact time on removal of Cu(II) were studied using batch adsorption experiments. The results show that the Cu(II) absorption strongly depends on pH and the optimum pH is 6. Compared with chitosan beads (CB), the BICB has higher efficiency and capacity on Cu(II) removal. The Langmuir isotherm model (R2=0.994) is proved to fit the equilibrium data best. The maximum adsorption capacity determined from Langmuir model is 100.70 mg/g. The kinetic data fit well with the pseudo-second-order model and the correlation coefficient is greater than 0.999. The biosorbents are successfully regenerated using 0.1 mol/L NaOH solution.