工业水处理
工業水處理
공업수처리
INDUSTRIAL WATER TREATMENT
2014年
5期
45-49
,共5页
纤维素%蒙脱土%纳米复合高吸水性树脂%亚甲基蓝
纖維素%矇脫土%納米複閤高吸水性樹脂%亞甲基藍
섬유소%몽탈토%납미복합고흡수성수지%아갑기람
cellulose%montmorillonite%nanocomposite super-absorptive resin%methylene blue
采用FTIR和SEM对纤维素-g-聚丙烯酸/丙烯酰胺/蒙脱土(LNC-g-PAA/AM/MMT)纳米复合高吸水性树脂的结构进行表征。研究亚甲基蓝染料的初始质量浓度、吸附时间、吸附温度和pH等不同条件下,对LNC-g-PAA/AM/MMT吸附该染料吸附量的影响。此外,在最佳条件吸附饱和时,改变解吸时间、HCl浓度等研究LNC-g-PAA/AM/MMT的解吸性能。结果表明:初始质量浓度为2500 mg/L,120 min,30℃,pH=5时,LNC-g-PAA/AM/MMT的吸附量高达2038.7 mg/g。整个过程很好地符合伪二级动力学模型和Langmuir等温线。在解吸时间120 min,HCl浓度0.05 mol/L时,解吸率高达73.16%。
採用FTIR和SEM對纖維素-g-聚丙烯痠/丙烯酰胺/矇脫土(LNC-g-PAA/AM/MMT)納米複閤高吸水性樹脂的結構進行錶徵。研究亞甲基藍染料的初始質量濃度、吸附時間、吸附溫度和pH等不同條件下,對LNC-g-PAA/AM/MMT吸附該染料吸附量的影響。此外,在最佳條件吸附飽和時,改變解吸時間、HCl濃度等研究LNC-g-PAA/AM/MMT的解吸性能。結果錶明:初始質量濃度為2500 mg/L,120 min,30℃,pH=5時,LNC-g-PAA/AM/MMT的吸附量高達2038.7 mg/g。整箇過程很好地符閤偽二級動力學模型和Langmuir等溫線。在解吸時間120 min,HCl濃度0.05 mol/L時,解吸率高達73.16%。
채용FTIR화SEM대섬유소-g-취병희산/병희선알/몽탈토(LNC-g-PAA/AM/MMT)납미복합고흡수성수지적결구진행표정。연구아갑기람염료적초시질량농도、흡부시간、흡부온도화pH등불동조건하,대LNC-g-PAA/AM/MMT흡부해염료흡부량적영향。차외,재최가조건흡부포화시,개변해흡시간、HCl농도등연구LNC-g-PAA/AM/MMT적해흡성능。결과표명:초시질량농도위2500 mg/L,120 min,30℃,pH=5시,LNC-g-PAA/AM/MMT적흡부량고체2038.7 mg/g。정개과정흔호지부합위이급동역학모형화Langmuir등온선。재해흡시간120 min,HCl농도0.05 mol/L시,해흡솔고체73.16%。
The structure of cellulose-g-p olyacrylic acid/acrylamide/montmorillonite nano-composite super-absorp-tive resin(LNC-g-PAA/AM/MMT) can be characterized by FTIR and SEM. Under different conditions,such as the initial mass concentration,adsorption time,adsorption temperature,pH,etc.,the effect of LNC-g-PAA/AM/MMT adsorption capacity on the adsorption quantity of the dye has been studied. In addition, on the basis of the optimum adsorptive saturation conditions,the desorption capacity of LNC-g-PAA/AM/MMT has been studied by changing the desorption time and HCl concentration. The results show that when the initial mass concentration is 2 500 mg/L ,ad-sorption time 120 min,adsorption temperature 30℃,and pH=5,the adsorption quantity of LNC-g-PAA/AM/MMT is as high as 2 038.7 mg/g. The whole process complies well with pseudo-second-order model and the Langmuir isotherm. When the desorption time is 120 min and HCl concentration 0.05 mol/L ,the highest desorption rate is as high as 73.16%.