CAJ | 학술논문

在溶液中，利用自组装方法制备以卟啉化合物为基础的纳米材料具有优良的光物理和光化学性质，在分子器件和人工模拟光合作用等方面具有巨大的应用前景，是目前的研究热点。本文详细介绍了单卟啉组装方法和多卟啉共组装方法，单卟啉组装包括双溶剂法和表面活性剂辅助法两类方法。简要介绍了卟啉自组装纳米材料在集光天线和光催化方面的应用。目前，自组装方法制备的卟啉化合物纳米材料已经出现了丰富的形态，但仍存在不足，即自组装作用机理有待深入研究，且如何将卟啉纳米材料的制备工艺放大并应用于实际，还有待进一步发展。
재용액중，이용자조장방법제비이계람화합물위기출적납미재료구유우량적광물리화광화학성질，재분자기건화인공모의광합작용등방면구유거대적응용전경，시목전적연구열점。본문상세개소료단계람조장방법화다계람공조장방법，단계람조장포괄쌍용제법화표면활성제보조법량류방법。간요개소료계람자조장납미재료재집광천선화광최화방면적응용。목전，자조장방법제비적계람화합물납미재료이경출현료봉부적형태，단잉존재불족，즉자조장작용궤리유대심입연구，차여하장계람납미재료적제비공예방대병응용우실제，환유대진일보발전。
Using self-assembly methods to prepare nanoscale porphyrin functional materials with excellent physicochemical properties has become a research focus , as it offers great potential application prospects for molecular devices and artificial photosynthesis. This review provides details for multiple-porphyrin as well as single-porphyrin self-assembly methods. In particular,mixing solvent techniques and surfactant-assisted method used in single-porphyrin self-assembly processes are discussed. Application of self-assembled porphyrin nanostructures in light-harvesting antenna and photocatalysis is summarized. Thus far,rich forms of porphyrin-based nanoarchitectures have been assembled. However,there is still a great need in understanding the self-assembly mechanisms and in further developing techniques for the practical applications of porphyrin nanostructures by self-assembly methods.