CAJ | 학술논문

甲醇同系化是一项很有前景的乙醇制备工艺，一般采用Ⅷ族金属可溶性盐作为催化剂，含碘化合物作为助催化剂。本文根据活性金属元素种类不同对甲醇同系化制乙醇催化体系进行分类，以此为基础对工艺条件优化、反应机理的研究现状进行了总结，指出现有催化剂体系乙醇产率偏低仍然是制约该工艺商业化的最大障碍。最后对甲醇同系化催化剂研究进行了展望，提出非均相多金属复合型催化剂的研制、非卤素类助剂的添加、低压稳定性甲醇同系化催化剂的开发是甲醇同系化研究的主要方向。
갑순동계화시일항흔유전경적을순제비공예，일반채용Ⅷ족금속가용성염작위최화제，함전화합물작위조최화제。본문근거활성금속원소충류불동대갑순동계화제을순최화체계진행분류，이차위기출대공예조건우화、반응궤리적연구현상진행료총결，지출현유최화제체계을순산솔편저잉연시제약해공예상업화적최대장애。최후대갑순동계화최화제연구진행료전망，제출비균상다금속복합형최화제적연제、비서소류조제적첨가、저압은정성갑순동계화최화제적개발시갑순동계화연구적주요방향。
The methanol homologation is one of the promising technologies for ethanol production. Soluble salts of group-Ⅷ metals are generally used as catalysts,and iodine compounds as promoters. In this paper,catalysts are categorized according to the variety of active metal elements,and the mechanism of methanol homologation reaction is analyzed based on the former category. The reported work indicated that the low ethanol yield was the major restriction for the commercialization of this technology. Finally,the outlook for the future development of methanol homologation catalyst and further investigation of mechanism is provided in light of the current research status,regarding composite catalyst with multimetallic,catalyst modified with no halogen element,as well as low pressure-resistant catalysts.