黄金科学技术
黃金科學技術
황금과학기술
GOLD SCIENCE AND TECHNOLOGY
2013年
5期
93-96
,共4页
夏光祥%段东平%周娥%陈思明%李婷
夏光祥%段東平%週娥%陳思明%李婷
하광상%단동평%주아%진사명%리정
含砷难冶金矿%催化氧化氨浸提金%雄黄转化%Cu2+催化%坪定金矿%甘肃省
含砷難冶金礦%催化氧化氨浸提金%雄黃轉化%Cu2+催化%坪定金礦%甘肅省
함신난야금광%최화양화안침제금%웅황전화%Cu2+최화%평정금광%감숙성
arsenic refractory gold%pressure oxidation of ammonia leaching of gold%realgar conversion%Cu2+catalysis%Pingding gold ore%Gansu Province
坪定金矿是富金高砷高碳难处理金矿,所含砷化合物为雌黄和(或)雄黄,普通处理工艺金的氰化率较低。针对坪定金矿特点,提出“加压催化氧化氨浸法”,成功地实现了坪定矿中金的有效回收。通过向氨性溶液中加入硫磺使雄黄转化为易溶于氨水中的雌黄,再通过氨水将矿物中的雄黄去除。最后,利用Cu2+的催化作用促使砷脱除过程中在金矿表面所形成的不溶性硫膜氧化,便于后续氰化提金的进行。经过该方法处理后的坪定金矿矿石金的氰化率可达到92%以上。由于采用氨性环境,该工艺中所用设备材料都为普通钢材,设备投资小,运行成本低,经济效益高,2年内可实现盈利。
坪定金礦是富金高砷高碳難處理金礦,所含砷化閤物為雌黃和(或)雄黃,普通處理工藝金的氰化率較低。針對坪定金礦特點,提齣“加壓催化氧化氨浸法”,成功地實現瞭坪定礦中金的有效迴收。通過嚮氨性溶液中加入硫磺使雄黃轉化為易溶于氨水中的雌黃,再通過氨水將礦物中的雄黃去除。最後,利用Cu2+的催化作用促使砷脫除過程中在金礦錶麵所形成的不溶性硫膜氧化,便于後續氰化提金的進行。經過該方法處理後的坪定金礦礦石金的氰化率可達到92%以上。由于採用氨性環境,該工藝中所用設備材料都為普通鋼材,設備投資小,運行成本低,經濟效益高,2年內可實現盈利。
평정금광시부금고신고탄난처리금광,소함신화합물위자황화(혹)웅황,보통처리공예금적청화솔교저。침대평정금광특점,제출“가압최화양화안침법”,성공지실현료평정광중금적유효회수。통과향안성용액중가입류광사웅황전화위역용우안수중적자황,재통과안수장광물중적웅황거제。최후,이용Cu2+적최화작용촉사신탈제과정중재금광표면소형성적불용성류막양화,편우후속청화제금적진행。경과해방법처리후적평정금광광석금적청화솔가체도92%이상。유우채용안성배경,해공예중소용설비재료도위보통강재,설비투자소,운행성본저,경제효익고,2년내가실현영리。
Pingding gold ore,which containing high level of carbon,arsenic (orpiment and (or) realgar),is a refractory gold.Its gold extraction ratio is very low by common treatment process.The gold extraction ratio increases up to 92% after treating by pressure oxidation of ammonia leaching process,invented by authors.By adding sulfur, realgar could convert to orpiment in ammonia,and could dissolve in ammonia and be removal.At last,an insoluble sulfur film formatted by arsenic removal on gold ore particle oxidizes by Cu2+catalyst.The costs of equipment and operation are significantly reduced than those of traditional pressure oxidation process because of its ammonia environment.Profitability could be achieved within two years.