化学反应工程与工艺
化學反應工程與工藝
화학반응공정여공예
CHEMICAL REACTION ENGINEERING AND TECHNOLOGY
2014年
2期
175-181,187
,共8页
唐豪%宗原%奚桢浩%赵玲
唐豪%宗原%奚楨浩%趙玲
당호%종원%해정호%조령
反应挤出%双螺杆挤出机%数值模拟
反應擠齣%雙螺桿擠齣機%數值模擬
반응제출%쌍라간제출궤%수치모의
reactive extrusion%twin screw extruder%numerical simulation
聚合物反应挤出过程不仅涉及挤出过程中流动、传热传质等化学工程问题,还必须考虑反应与挤出过程的耦合。为控制产物的分子量及其分布,需对聚合物在挤出机中流动行为进行考察。理论计算为反应挤出分析提供了优化方法,其中反应器流型模拟可用于操作优化,而数值计算方法可用于设计优化。本文分析了反应挤出过程的模拟方法与发展现状,评估了当前研发需求,并对今后发展方向做了展望。
聚閤物反應擠齣過程不僅涉及擠齣過程中流動、傳熱傳質等化學工程問題,還必鬚攷慮反應與擠齣過程的耦閤。為控製產物的分子量及其分佈,需對聚閤物在擠齣機中流動行為進行攷察。理論計算為反應擠齣分析提供瞭優化方法,其中反應器流型模擬可用于操作優化,而數值計算方法可用于設計優化。本文分析瞭反應擠齣過程的模擬方法與髮展現狀,評估瞭噹前研髮需求,併對今後髮展方嚮做瞭展望。
취합물반응제출과정불부섭급제출과정중류동、전열전질등화학공정문제,환필수고필반응여제출과정적우합。위공제산물적분자량급기분포,수대취합물재제출궤중류동행위진행고찰。이론계산위반응제출분석제공료우화방법,기중반응기류형모의가용우조작우화,이수치계산방법가용우설계우화。본문분석료반응제출과정적모의방법여발전현상,평고료당전연발수구,병대금후발전방향주료전망。
Reactive extrusion involves not only flow behavior, mass and heat transfer in the extrusion process, but also the coupling of reaction and extrusion. The flow behavior of polymer melt/solution in extruder should be investigated in order to control the molecular weight and its distribution. Theoretical calculation has been widely used to optimize reactive extrusion process, which contains two main categories:the approaches based on chemical engineering and the others based on continuum mechanics. The formers are benefit to operation optimization, while the latters are helpful for design optimization. The developments of these two approaches are reviewed in this paper and main trends of simulation for reactive extrusion are also discussed.