CAJ | 학술논문

以对甲苯磺酸铁为氧化剂，采用化学氧化法在阀金属钽多孔体表面电介质层上合成了具有优异导电性能的导电聚合物聚3,4-乙烯基二氧噻吩（PEDT）。并以PEDT为阴极电解质取代传统的阴极电解质二氧化锰制备有机固体钽电解电容器，对有机固体钽电解电容器的频率及温度特性进行研究。结果表明，以PEDT为阴极电解质的钽电解电容器，其等效串联电阻（ESR）值降低至传统无机固体钽电解电容器ESR值的1/3以下，具有稳定的频率特性和温度特性,能够满足现代高频开关电源滤波电路的特殊要求。
이대갑분광산철위양화제，채용화학양화법재벌금속단다공체표면전개질층상합성료구유우이도전성능적도전취합물취3,4-을희기이양새분（PEDT）。병이PEDT위음겁전해질취대전통적음겁전해질이양화맹제비유궤고체단전해전용기，대유궤고체단전해전용기적빈솔급온도특성진행연구。결과표명，이PEDT위음겁전해질적단전해전용기，기등효천련전조（ESR）치강저지전통무궤고체단전해전용기ESR치적1/3이하，구유은정적빈솔특성화온도특성,능구만족현대고빈개관전원려파전로적특수요구。
Ferric p-toluenesulfonate as oxidant, using chemical oxidation method, the conductive polymer poly 3,4-vinyl dioxythiophene (PEDT) with high conductive was synthesized on the surface of the dielectric layer on the valve metal tantalum porous sintered compact. And replacing the traditional manganese dioxide with the PEDT as cathode electrolyte to make organic tantalum solid electrolytic capacitors, frequency and temperature characteristics of these organic tantalum solid electrolytic capacitors were studied. The results showed that the equivalent series resistance (ESR) value of the tantalum electrolytic capacitor with PEDT as cathode electrolyte decreased to1/3 or less of traditional inorganic solid tantalum electrolytic capacitor ESR value, and have stable frequency characteristics and temperature characteristics, meet the modern high-frequency switching power supply filter circuit specific requirements.