化学分析计量
化學分析計量
화학분석계량
CHEMICAL ANALYSIS AND METERAGE
2014年
2期
47-49,59
,共4页
刘丽丽%徐少才%谭丕功%石仁德%宋志法
劉麗麗%徐少纔%譚丕功%石仁德%宋誌法
류려려%서소재%담비공%석인덕%송지법
灭多威肟%高效液相色谱%固相萃取%液液萃取
滅多威肟%高效液相色譜%固相萃取%液液萃取
멸다위우%고효액상색보%고상췌취%액액췌취
methomyl-oxime%HPLC%liquid-solid extraction%liquid-liquid extraction
采用Oasis HLB固相萃取柱萃取水中灭多威肟，建立了固相萃取高效液相色谱法测定水中灭多威肟的分析方法。首先用10 mL甲醇和10 mL超纯水活化Oasis HLB固相萃取柱，以1 mL/min的流速萃取100 mL水样，用10 mL甲醇洗脱，浓缩洗脱液至1 mL后采用液相色谱法测定，甲醇-水（35∶65）为流动相，检测波长为230 nm。该方法检出限为0.14μg/L，测定结果的相对标准偏差为1.41%～2.08%，平均回收率为86.8%～88.4%。该法适用于工业废水中灭多威肟的测定。
採用Oasis HLB固相萃取柱萃取水中滅多威肟，建立瞭固相萃取高效液相色譜法測定水中滅多威肟的分析方法。首先用10 mL甲醇和10 mL超純水活化Oasis HLB固相萃取柱，以1 mL/min的流速萃取100 mL水樣，用10 mL甲醇洗脫，濃縮洗脫液至1 mL後採用液相色譜法測定，甲醇-水（35∶65）為流動相，檢測波長為230 nm。該方法檢齣限為0.14μg/L，測定結果的相對標準偏差為1.41%～2.08%，平均迴收率為86.8%～88.4%。該法適用于工業廢水中滅多威肟的測定。
채용Oasis HLB고상췌취주췌취수중멸다위우，건립료고상췌취고효액상색보법측정수중멸다위우적분석방법。수선용10 mL갑순화10 mL초순수활화Oasis HLB고상췌취주，이1 mL/min적류속췌취100 mL수양，용10 mL갑순세탈，농축세탈액지1 mL후채용액상색보법측정，갑순-수（35∶65）위류동상，검측파장위230 nm。해방법검출한위0.14μg/L，측정결과적상대표준편차위1.41%～2.08%，평균회수솔위86.8%～88.4%。해법괄용우공업폐수중멸다위우적측정。
Oasis HLB column liquid-solid extraction-HPLC method for analyzing methomyl-oxime in water was introduced. Oasis HLB column was activated with 10 mL methanol and 10 mL ultrapure water firstly, then 100 mL water sample passed the column at the rate of 1 mL/min, and the column was eluted with 10 mL methanol, the eluant was concentrated to 1 mL and determined with HPLC, metanol-water(35∶65) as the mobile phase, at the detection wavelenth of 230 nm. The detection limit was 0.14μg/L, RSD was 1.41%-2.08%, and the average recovery was 86.8%-88.4%. The method may be used to determine methomyl-oxime in waste water.
