CAJ | 학술논문

从光化学锂同位素分离实验研究的需求出发，基于其分离条件，提出了一种测量锂同位素比率的方法。该方法利用锂原子蒸气对探测光吸收峰的峰值来计算锂的同位素比率，避开了测量原子密度时所需的吸收信号频率定标与光强随频率变化积分中积分限的选择问题。该方法还根据锂同位素吸收谱的特殊性采用具有较强吸收效应的6 Li的D2线对应的吸收峰峰值，可在原子蒸气中6 Li含量较低时提高对比率的测量精度。设计并搭建了实验装置，对该方法进行了测试。同一条件下所测得的同位素比率相对标准偏差小于1％，表明该方法对光化学分离方法中锂同位素比率相对变化是敏感的。这意味着该方法可作为以原子蒸气为分离介质的激光锂同位素分离研究的诊断手段。
종광화학리동위소분리실험연구적수구출발，기우기분리조건，제출료일충측량리동위소비솔적방법。해방법이용리원자증기대탐측광흡수봉적봉치래계산리적동위소비솔，피개료측량원자밀도시소수적흡수신호빈솔정표여광강수빈솔변화적분중적분한적선택문제。해방법환근거리동위소흡수보적특수성채용구유교강흡수효응적6 Li적D2선대응적흡수봉봉치，가재원자증기중6 Li함량교저시제고대비솔적측량정도。설계병탑건료실험장치，대해방법진행료측시。동일조건하소측득적동위소비솔상대표준편차소우1％，표명해방법대광화학분리방법중리동위소비솔상대변화시민감적。저의미착해방법가작위이원자증기위분리개질적격광리동위소분리연구적진단수단。
A method for measuring the isotope ratio in a photo-chemical lithium isotope separation process based on separation conditions was proposed . Instead of doing integration around the absorption peaks ,which was often conducted in calculating the isotope ratio from experimental curves , the peak’ s values were used to compute the isotope ratio of the lithium .The advantage of this procedure is that the complicated scaling operation for experimental curves can be avoided .The use of D2 line of 6 Li with stronger absorption effect can help to improve the measurement precision w hen the content of 6 Li in atomic vapor is low .An experimental setup was built and tested .In one experimental condition the relative standard deviation of the measured isotope ratio is less than 1% ,w hich show s that the method is sensitive to the change of the isotope ratio in a photo-chemical lithium isotope separation process .It means that the method is applicable as a diagnostic tool in the study of lithium atomic vapor laser isotope separation .