天然气化工
天然氣化工
천연기화공
NATURAL GAS CHEMICAL INDUSTRY
2013年
4期
47-48
,共2页
C10叔碳酸%生产工艺%分离%改进
C10叔碳痠%生產工藝%分離%改進
C10숙탄산%생산공예%분리%개진
neodecanoic acid%production process%separation%improvement
以壬烯、水和一氧化碳为原料,在浓硫酸-羰基铜的催化下生产C10叔碳酸,应用改进的分离方法,加不大于反应所需的水量就可以使产品叔碳酸和催化剂高效地分离开来,实现了催化剂直接循环使用,避免了稀硫酸排放量大、污染严重的缺陷。
以壬烯、水和一氧化碳為原料,在濃硫痠-羰基銅的催化下生產C10叔碳痠,應用改進的分離方法,加不大于反應所需的水量就可以使產品叔碳痠和催化劑高效地分離開來,實現瞭催化劑直接循環使用,避免瞭稀硫痠排放量大、汙染嚴重的缺陷。
이임희、수화일양화탄위원료,재농류산-탄기동적최화하생산C10숙탄산,응용개진적분리방법,가불대우반응소수적수량취가이사산품숙탄산화최화제고효지분리개래,실현료최화제직접순배사용,피면료희류산배방량대、오염엄중적결함。
A novel process with improving separation was used to synthesize neodecanoic acid from nonene, water and carbon monoxide with concentrated sulfuric acid-copper carbonyl as catalyst, in which the catalyst and the product could be separated effectively by adding less amount of water than that needed for the reaction, so the catalyst could be recycled directly and the serious pollution caused by the emission of large quantity of dilute sulfuric acid could be avoided.