稀土学报(英文版)
稀土學報(英文版)
희토학보(영문판)
JOURNAL OF RARE EARTHS
2013年
9期
843-848
,共6页
胡金民%周大成%王荣飞%陈明厚%焦清%余雪%邱建备
鬍金民%週大成%王榮飛%陳明厚%焦清%餘雪%邱建備
호금민%주대성%왕영비%진명후%초청%여설%구건비
up-conversion%Ba2LaF7%nanocrystals%glass-ceramics%rare earths
The up-conversion of Er3+/Yb3+co-doped transparent glass-ceramics 50SiO2-10AlF3-5TiO2-30BaF2-4LaF3-0.5ErF3-0.5YbF3 containing Ba2LaF7 nanocrystals under the changing of heat treatment temperature and time were investigated. The Ba2LaF7 nanocrystals precipitated from the glass matrix was confirmed by X-ray diffraction (XRD). The structural investigation carried out by XRD and trans-mission electron microscopy (TEM) evidenced the formation of cubic Ba2LaF7 nanocrystals with crystal size of about 14 nm. Comparing with the samples before heat treatment, the high efficiency up-conversion emission of Er3+/Yb3+co-doped samples was observed in the glass-ceramics under 980 nm laser diode excitation. The increase in red emission intensity bands was stronger than the green bands when the crystal size increased. The mechanism for the up-conversion process in the glass-ceramics and the reasons for the increase of Er3+/Yb3+co-doped up-conversion intensity after heat treatment were discussed.