CAJ | 학술논문

基于溶剂热法合成出金属有机骨架材料Co-BTC，通过XRD、IR表征其结构。采用固定床吸附穿透实验，考察了不同的空速条件及溶解水对Co-BTC吸附分离噻吩的影响，并用甲苯溶剂洗涤进行吸附剂再生。结果表明，Co-BTC对模型油中噻吩的穿透容量及饱和吸附量分别为0.98％，2.05%(wt)；Co-BTC在含溶解水和纯模型油中硫的饱和容量分别是1.50％，2.05％，饱和吸附容量降低了27％，运用分子筛分层填装吸附柱技术能将Co-BTC的饱和吸附容量提高到2.02％；再生的吸附剂对模型油中噻吩硫的饱和吸附容量为2.02％，再生率达到99％。
기우용제열법합성출금속유궤골가재료Co-BTC，통과XRD、IR표정기결구。채용고정상흡부천투실험，고찰료불동적공속조건급용해수대Co-BTC흡부분리새분적영향，병용갑분용제세조진행흡부제재생。결과표명，Co-BTC대모형유중새분적천투용량급포화흡부량분별위0.98％，2.05%(wt)；Co-BTC재함용해수화순모형유중류적포화용량분별시1.50％，2.05％，포화흡부용량강저료27％，운용분자사분층전장흡부주기술능장Co-BTC적포화흡부용량제고도2.02％；재생적흡부제대모형유중새분류적포화흡부용량위2.02％，재생솔체도99％。
Metal-organic framework compound Co-BTC was synthesized under hydrothermal conditions and characterized by XRD and IR. Effects of airspeed and moisture content on adsorptive separation of thiophene by Co-BTC were studied by fixed adsorption bed breakthrough curve, and the adsorbent was reactivated through solvent toluene washing. The results show that ,with the increase of airspeed, saturated adsorption capacity of Co-BTC reduces;sulfur saturated adsorption capacities of Co-BTC with water and without water are 1.50%and 2.05%(wt) respectively, desulfurization saturated adsorption capacity was reduced by 27%.To use molecular sieve stratification fill adsorption column technique can increase Co-BTC saturated adsorption capacity to 2.02 %, saturated adsorption capacity of regenerated adsorbent for thiophenic sulfur in model oil is 2.02%, regeneration rate reaches 99%.