化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2013年
10期
2434-2439
,共6页
超高温陶瓷%ZrB2陶瓷%前体转化陶瓷
超高溫陶瓷%ZrB2陶瓷%前體轉化陶瓷
초고온도자%ZrB2도자%전체전화도자
ultrahigh temperature ceramics(UHTCs)%zirconium boride%polymer-derived ceramics
航天航空、新兵器、新能源等高科技领域的快速发展对超高温陶瓷材料提出了迫切的需求,ZrB2陶瓷材料是最重要的超高温陶瓷材料之一。本文阐明了ZrB2陶瓷拥有优异性能的原因,综述了ZrB2陶瓷材料的制备研究进展,介绍了固相法、气相法、前体法制备ZrB2陶瓷材料的机理,对比了各种ZrB2陶瓷材料制备方法的优缺点,并指出了有机前体转化法具有可设计性好、不含杂质元素、成型可控、陶瓷转化温度低等优点。本文总结得出有机前体转化法是制备ZrB2超高温陶瓷复合材料较理想的方法,以及基于有机聚合物的ZrB2陶瓷前体是未来重要的发展方向之一。
航天航空、新兵器、新能源等高科技領域的快速髮展對超高溫陶瓷材料提齣瞭迫切的需求,ZrB2陶瓷材料是最重要的超高溫陶瓷材料之一。本文闡明瞭ZrB2陶瓷擁有優異性能的原因,綜述瞭ZrB2陶瓷材料的製備研究進展,介紹瞭固相法、氣相法、前體法製備ZrB2陶瓷材料的機理,對比瞭各種ZrB2陶瓷材料製備方法的優缺點,併指齣瞭有機前體轉化法具有可設計性好、不含雜質元素、成型可控、陶瓷轉化溫度低等優點。本文總結得齣有機前體轉化法是製備ZrB2超高溫陶瓷複閤材料較理想的方法,以及基于有機聚閤物的ZrB2陶瓷前體是未來重要的髮展方嚮之一。
항천항공、신병기、신능원등고과기영역적쾌속발전대초고온도자재료제출료박절적수구,ZrB2도자재료시최중요적초고온도자재료지일。본문천명료ZrB2도자옹유우이성능적원인,종술료ZrB2도자재료적제비연구진전,개소료고상법、기상법、전체법제비ZrB2도자재료적궤리,대비료각충ZrB2도자재료제비방법적우결점,병지출료유궤전체전화법구유가설계성호、불함잡질원소、성형가공、도자전화온도저등우점。본문총결득출유궤전체전화법시제비ZrB2초고온도자복합재료교이상적방법,이급기우유궤취합물적ZrB2도자전체시미래중요적발전방향지일。
Zirconium boride is one of the most important ultrahigh temperature ceramics(UHTCs), which are urgently required for the development of the aerospace,advanced weapons,and energy. In this paper the reasons for excellent function of zirconium boride are discussed,and the progress of preparation of zirconium boride is reviewed. The mechanisms of preparation processes of zirconium boride,such as soild-phase methods,vapor-phase methods,and precursor methods are introduced. Their advantages and disadvantages are compared. Accordingly,polymer-derived ceramic is an ideal processy for preparing zirconium boride ultrahigh temperature ceramic matrix composites for its easy design,high purity,controllable molding and low transform temperature. So the study on polymer precursor of zirconium boride ceramics would be one of the most important directions of development.