化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2013年
10期
2409-2415
,共7页
李广伟%鲁俊民%秦东振%詹自力%郭雪原
李廣偉%魯俊民%秦東振%詹自力%郭雪原
리엄위%로준민%진동진%첨자력%곽설원
离子液体%电解质%电化学%气体传感器
離子液體%電解質%電化學%氣體傳感器
리자액체%전해질%전화학%기체전감기
ionic liquids%electrolyte%electrochemistry%gas sensors
离子液体作为一种新型电解质,有着优良的电化学性能,有望解决电化学气体传感器在高温、高湿下使用寿命短、稳定性差等问题。本文按照被检测气体种类对离子液体作为电解质的电流型电化学气体传感器进行了综述,就其在不同气体中的灵敏度、电化学响应、稳定性、气体传质、反应机理等方面的研究加以阐述。从灵敏度、响应时间、稳定性、选择性、抗干扰性等方面介绍了离子液体电化学气体传感器的优缺点,并对目前离子液体电化学气体传感器研究中存在的不足做了评述。同时指出未来应该加强在大气条件下电化学气体传感器性能、响应机理和电化学反应历程的研究。
離子液體作為一種新型電解質,有著優良的電化學性能,有望解決電化學氣體傳感器在高溫、高濕下使用壽命短、穩定性差等問題。本文按照被檢測氣體種類對離子液體作為電解質的電流型電化學氣體傳感器進行瞭綜述,就其在不同氣體中的靈敏度、電化學響應、穩定性、氣體傳質、反應機理等方麵的研究加以闡述。從靈敏度、響應時間、穩定性、選擇性、抗榦擾性等方麵介紹瞭離子液體電化學氣體傳感器的優缺點,併對目前離子液體電化學氣體傳感器研究中存在的不足做瞭評述。同時指齣未來應該加彊在大氣條件下電化學氣體傳感器性能、響應機理和電化學反應歷程的研究。
리자액체작위일충신형전해질,유착우량적전화학성능,유망해결전화학기체전감기재고온、고습하사용수명단、은정성차등문제。본문안조피검측기체충류대리자액체작위전해질적전류형전화학기체전감기진행료종술,취기재불동기체중적령민도、전화학향응、은정성、기체전질、반응궤리등방면적연구가이천술。종령민도、향응시간、은정성、선택성、항간우성등방면개소료리자액체전화학기체전감기적우결점,병대목전리자액체전화학기체전감기연구중존재적불족주료평술。동시지출미래응해가강재대기조건하전화학기체전감기성능、향응궤리화전화학반응역정적연구。
Ionic liquids,as a new type of electrolyte,are expected to solve the problem of short life, poor stability of electrochemical gas sensors at high ambient humidity and temperature. The applications of ionic liquids as electrolyte solution in electrochemical gas sensors were reviewed according to the species of the gases. The studies on sensitivity,electrochemical response,stability, gas mass transfer and reaction mechanism of different gases were presented. The advantages and disadvantages of ionic liquid electrochemical gas sensors were discussed from the aspects of sensitivity,response time,stability,selectivity and anti-interference. The imperfections of current research on ionic liquids in electrochemical gas sensor were introduced. Moreover,future research on electrochemical gas sensors was suggested. Under atmospheric condition,the study on properties of sensors,response mechanism and electrochemical reaction process should be emphasized in the future.