化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2013年
10期
2274-2278,2301
,共6页
双极膜%电渗析%水解离%液流电池
雙極膜%電滲析%水解離%液流電池
쌍겁막%전삼석%수해리%액류전지
bipolar membrane%electro-dialysis%water dissociation%redox flow battery
双极膜通过对水解离具有的催化效应,能够使水中的盐重新转变为酸和碱,在环境保护和资源回收等领域发挥着越来越大的作用。本文解析了双极膜的“三明治”结构特点、发展历程及发展趋势、制备工艺技术,阐述了双极膜催化水解离机理的3个模型:第二Wien效应模型、化学反应模型以及中和层模型。探究了双极膜电渗析及与其它化工过程耦合技术在不同领域的应用,其中包括酸碱生产领域、资源分离回收领域以及污染控制领域等。分析了双极膜的具体应用过程中存在的局限性并展望了双极膜在水解制氢、液流电池方面的应用前景。指出双极膜将朝着与传统化工过程、新型液流电池等系统集成化、规模化方向发展,成为多种化工应用领域的重要组件。
雙極膜通過對水解離具有的催化效應,能夠使水中的鹽重新轉變為痠和堿,在環境保護和資源迴收等領域髮揮著越來越大的作用。本文解析瞭雙極膜的“三明治”結構特點、髮展歷程及髮展趨勢、製備工藝技術,闡述瞭雙極膜催化水解離機理的3箇模型:第二Wien效應模型、化學反應模型以及中和層模型。探究瞭雙極膜電滲析及與其它化工過程耦閤技術在不同領域的應用,其中包括痠堿生產領域、資源分離迴收領域以及汙染控製領域等。分析瞭雙極膜的具體應用過程中存在的跼限性併展望瞭雙極膜在水解製氫、液流電池方麵的應用前景。指齣雙極膜將朝著與傳統化工過程、新型液流電池等繫統集成化、規模化方嚮髮展,成為多種化工應用領域的重要組件。
쌍겁막통과대수해리구유적최화효응,능구사수중적염중신전변위산화감,재배경보호화자원회수등영역발휘착월래월대적작용。본문해석료쌍겁막적“삼명치”결구특점、발전역정급발전추세、제비공예기술,천술료쌍겁막최화수해리궤리적3개모형:제이Wien효응모형、화학반응모형이급중화층모형。탐구료쌍겁막전삼석급여기타화공과정우합기술재불동영역적응용,기중포괄산감생산영역、자원분리회수영역이급오염공제영역등。분석료쌍겁막적구체응용과정중존재적국한성병전망료쌍겁막재수해제경、액류전지방면적응용전경。지출쌍겁막장조착여전통화공과정、신형액류전지등계통집성화、규모화방향발전,성위다충화공응용영역적중요조건。
Salts in water can be dissociated to acid and base in the presence of bipolar membranes (BPMs),which acts as catalyst in the process of water dissociation. Therefore,BMPs could be used in environmental protection and resource recycling. This paper reviewed technology progresses in BPMs, including preparation,characteristics,integration of BMPs and pollution control applications. Three major models BPMs for catalyzing water dissociation were introduced. Applications of BMPs in environmental protection were also introduced. Moreover,the prospects of BPMs applications in redox flow batteries and hydrolysis hydrogen production were also presented,and the limitations of current BPMs were discussed. The integration of BMPs with other chemical processes,and application for redox flow batteries can be prospective in future research.