上海大学学报(自然科学版)
上海大學學報(自然科學版)
상해대학학보(자연과학판)
JOURNAL OF SHANGHAI UNIVERSITY (NATURAL SCIENCE EDITION)
2014年
1期
51-58
,共8页
冯志海%樊桢%孔清%余立琼%徐林
馮誌海%樊楨%孔清%餘立瓊%徐林
풍지해%번정%공청%여립경%서림
高导热碳/碳复合材料%中间相沥青%中间相沥青基碳纤维
高導熱碳/碳複閤材料%中間相瀝青%中間相瀝青基碳纖維
고도열탄/탄복합재료%중간상력청%중간상력청기탄섬유
high thermal conductivity C/C composite%mesophase pitch%mesophase pitch-based carbon fiber
以中间相沥青和中间相沥青基碳纤维为原料,采用碳布热压法、液相浸渍法制备了二维和三维高导热碳/碳复合材料,且所制得复合材料的热导率分别高达443和340 W/(m·K)。依据碳/碳复合材料的热导率模型,分析了不同结构特征参数对材料热导率的影响。结果表明,基体碳热导率、孔隙率以及界面相厚度均会在一定程度上影响材料的导热性能。
以中間相瀝青和中間相瀝青基碳纖維為原料,採用碳佈熱壓法、液相浸漬法製備瞭二維和三維高導熱碳/碳複閤材料,且所製得複閤材料的熱導率分彆高達443和340 W/(m·K)。依據碳/碳複閤材料的熱導率模型,分析瞭不同結構特徵參數對材料熱導率的影響。結果錶明,基體碳熱導率、孔隙率以及界麵相厚度均會在一定程度上影響材料的導熱性能。
이중간상력청화중간상력청기탄섬유위원료,채용탄포열압법、액상침지법제비료이유화삼유고도열탄/탄복합재료,차소제득복합재료적열도솔분별고체443화340 W/(m·K)。의거탄/탄복합재료적열도솔모형,분석료불동결구특정삼수대재료열도솔적영향。결과표명,기체탄열도솔、공극솔이급계면상후도균회재일정정도상영향재료적도열성능。
2D high thermal conductivity C/C composite and 3D high thermal conductiv-ity C/C composite were produced through hot pressing and liquid impregnating method, with mesophase pitch-based carbon fiber and mesophase pitch as raw materials. Ther-mal conductivity as high as 443 W/(m·K) and 340 W/(m·K) was achieved for 2D high thermal conductivity C/C composite and 3D high thermal conductivity C/C composite, respectively. The effects of structure parameters on the thermal conductivity were ana-lyzed according to the analytical thermal model of C/C composites. The results show that thermal conductivity of carbon matrix, porosity and interface have different effects on the thermal conductivity of composites.