功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
19期
2882-2887
,共6页
冉奋%张宣宣%王翎任%赵磊%范会利%孔令斌%康龙
冉奮%張宣宣%王翎任%趙磊%範會利%孔令斌%康龍
염강%장선선%왕령임%조뢰%범회리%공령빈%강룡
超级电容器%水热法%MnO2%电极材料
超級電容器%水熱法%MnO2%電極材料
초급전용기%수열법%MnO2%전겁재료
supercapacitor%hydrothermal method%manganese dioxide%electrode material
在不同的反应时间下水热法控制制备发射状超级电容器用Mn O 2电极材料,采用 X射线衍射光谱(XRD)、扫描电镜(SEM)表征其结构,采用循环伏安、恒流充放电和交流阻抗研究其电化学电容性能。结果表明,制备的Mn O 2为隐钾锰矿型,具有发射状结构,随着反应时间的延长,Mn O 2的晶型从不完善逐渐变得完善,发射状结构逐渐明显、增大,并且 Mn O 2辐射出的每根单枝从较细的纳米刺逐渐生长为四方结构的纳米棒;在5 mA/cm2的电流密度下,最高比电容达到了448F/g;随着反应时间的增加,MnO2电极的比容量先增长再降低。
在不同的反應時間下水熱法控製製備髮射狀超級電容器用Mn O 2電極材料,採用 X射線衍射光譜(XRD)、掃描電鏡(SEM)錶徵其結構,採用循環伏安、恆流充放電和交流阻抗研究其電化學電容性能。結果錶明,製備的Mn O 2為隱鉀錳礦型,具有髮射狀結構,隨著反應時間的延長,Mn O 2的晶型從不完善逐漸變得完善,髮射狀結構逐漸明顯、增大,併且 Mn O 2輻射齣的每根單枝從較細的納米刺逐漸生長為四方結構的納米棒;在5 mA/cm2的電流密度下,最高比電容達到瞭448F/g;隨著反應時間的增加,MnO2電極的比容量先增長再降低。
재불동적반응시간하수열법공제제비발사상초급전용기용Mn O 2전겁재료,채용 X사선연사광보(XRD)、소묘전경(SEM)표정기결구,채용순배복안、항류충방전화교류조항연구기전화학전용성능。결과표명,제비적Mn O 2위은갑맹광형,구유발사상결구,수착반응시간적연장,Mn O 2적정형종불완선축점변득완선,발사상결구축점명현、증대,병차 Mn O 2복사출적매근단지종교세적납미자축점생장위사방결구적납미봉;재5 mA/cm2적전류밀도하,최고비전용체도료448F/g;수착반응시간적증가,MnO2전겁적비용량선증장재강저。
Emission-like manganese dioxide was controlled synthesized by using the hydrothermal method in the different reaction time for supercapacitor electrode.The structures were characterized by XRD and SEM,and the supercapacitive behaviors were investigated by cyclic voltammetry (CV),charge-discharge tests,and ac im-pedance spectroscopy,respectively.The results suggested that the as-prepared manganese dioxides indexed tet-ragonal cryptomelane phase and the morphology of which was emission-like nanoclusters.Crystallinity and structure dimension became larger and the nanostab structure of every single branch was changed into nanorod structure followed with the time.The specific capacitance values of manganese dioxide electrode was 448F/g corresponding to the charge/discharge current densities of 5 mA/cm2 .With the prolonging of reaction time,the specific capacitance tended to raise first and then declined.