功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
19期
2878-2881,2887
,共5页
杨越%徐盛明%翁雅青%黄国勇%李林艳
楊越%徐盛明%翁雅青%黃國勇%李林豔
양월%서성명%옹아청%황국용%리림염
锂离子电池%共沉淀%正极材料%xLi2 MnO3 ·(1-x)Li(Ni1/3 Co1/3 Mn1/3 )O2
鋰離子電池%共沉澱%正極材料%xLi2 MnO3 ·(1-x)Li(Ni1/3 Co1/3 Mn1/3 )O2
리리자전지%공침정%정겁재료%xLi2 MnO3 ·(1-x)Li(Ni1/3 Co1/3 Mn1/3 )O2
lithium-ion battery%hydroxide co-precipitation method%cathode material%xLi2 MnO3 · (1-x )Li (Ni1/3 Co1/3 Mn1/3 )O2
以氨水作为络合剂,采用氢氧化物共沉淀法合成了球形富锂锰基正极材料xLi2 MnO3·(1-x)Li (Ni1/3Co1/3Mn1/3)O2(x=0.2、0.4和0.6),并对合成的不同组分样品材料的化学成分、结构、形貌和电化学性能进行了表征。结果表明,样品材料的化学组分与其理论含量相同,随着x 的增大,材料的粒度变小,在电压范围为2.5~4.6V 条件下进行充放电性能测试时,材料的首次充放电容量随着x 值减小而增加,且当x=0.2时,材料在不同倍率条件下具有最大的放电容量。
以氨水作為絡閤劑,採用氫氧化物共沉澱法閤成瞭毬形富鋰錳基正極材料xLi2 MnO3·(1-x)Li (Ni1/3Co1/3Mn1/3)O2(x=0.2、0.4和0.6),併對閤成的不同組分樣品材料的化學成分、結構、形貌和電化學性能進行瞭錶徵。結果錶明,樣品材料的化學組分與其理論含量相同,隨著x 的增大,材料的粒度變小,在電壓範圍為2.5~4.6V 條件下進行充放電性能測試時,材料的首次充放電容量隨著x 值減小而增加,且噹x=0.2時,材料在不同倍率條件下具有最大的放電容量。
이안수작위락합제,채용경양화물공침정법합성료구형부리맹기정겁재료xLi2 MnO3·(1-x)Li (Ni1/3Co1/3Mn1/3)O2(x=0.2、0.4화0.6),병대합성적불동조분양품재료적화학성분、결구、형모화전화학성능진행료표정。결과표명,양품재료적화학조분여기이론함량상동,수착x 적증대,재료적립도변소,재전압범위위2.5~4.6V 조건하진행충방전성능측시시,재료적수차충방전용량수착x 치감소이증가,차당x=0.2시,재료재불동배솔조건하구유최대적방전용량。
Spherical cathode materials xLi2MnO3·(1-x)Li(Ni1/3Co1/3Mn1/3)O2(x=0.2,0.4 and 0.6),using ammonia as complexing agent,were synthesized by hydroxide co-precipitation method.Chemical component, structure,morphology and electrochemical performance of synthesized materials with diverse components were characterized by EDS,ICP,XRD,SEM and electrochemical performance measurement.Results show that chemical component of synthesized material was identical to its theoretical content.Increasing x value,particle size diminishes.Testing its charge-discharge performance under voltage ranging from 2.5 to 4.6V,first charge-discharge capacity increases as a function of x value and maximum discharge capacity at different ratios was reached when x=0 .2 .