功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
19期
2759-2763
,共5页
肖海河%刘洪波%何月德%简志敏%匡加才
肖海河%劉洪波%何月德%簡誌敏%劻加纔
초해하%류홍파%하월덕%간지민%광가재
锂离子电池%微晶石墨%炭包覆%真空浸渍
鋰離子電池%微晶石墨%炭包覆%真空浸漬
리리자전지%미정석묵%탄포복%진공침지
lithium-ion batteries%carbon coating%vacuum impregnation%graphite anode
针对微晶石墨振实密度低和首次库仑效率低的缺点,采用真空浸渍-炭化工艺对微晶石墨进行沥青炭包覆改性,利用XRD、拉曼光谱和 SEM等分析了炭包覆前后微晶石墨的结构和表面形貌,利用比表面测试仪测试了样品的BET比表面积,利用振实密度仪测定振实密度,并通过恒电流充放电和循环伏安等测试了样品的电化学性能。结果表明,炭包覆后微晶石墨的石墨化度略有降低,拉曼R 值由0.63增大至0.85;颗粒表面更光滑平整,BET 比表面积降低0.9m2/g,振实密度从0.95g/cm3提高至1.08g/cm3;不可逆容量损失从121mAh/g减小到44mAh/g,可逆容量从300mAh/g 提高到320mAh/g,首次库仑效率从71.2%提高到87.4%,而且循环性能得到明显改善。
針對微晶石墨振實密度低和首次庫崙效率低的缺點,採用真空浸漬-炭化工藝對微晶石墨進行瀝青炭包覆改性,利用XRD、拉曼光譜和 SEM等分析瞭炭包覆前後微晶石墨的結構和錶麵形貌,利用比錶麵測試儀測試瞭樣品的BET比錶麵積,利用振實密度儀測定振實密度,併通過恆電流充放電和循環伏安等測試瞭樣品的電化學性能。結果錶明,炭包覆後微晶石墨的石墨化度略有降低,拉曼R 值由0.63增大至0.85;顆粒錶麵更光滑平整,BET 比錶麵積降低0.9m2/g,振實密度從0.95g/cm3提高至1.08g/cm3;不可逆容量損失從121mAh/g減小到44mAh/g,可逆容量從300mAh/g 提高到320mAh/g,首次庫崙效率從71.2%提高到87.4%,而且循環性能得到明顯改善。
침대미정석묵진실밀도저화수차고륜효솔저적결점,채용진공침지-탄화공예대미정석묵진행력청탄포복개성,이용XRD、랍만광보화 SEM등분석료탄포복전후미정석묵적결구화표면형모,이용비표면측시의측시료양품적BET비표면적,이용진실밀도의측정진실밀도,병통과항전류충방전화순배복안등측시료양품적전화학성능。결과표명,탄포복후미정석묵적석묵화도략유강저,랍만R 치유0.63증대지0.85;과립표면경광활평정,BET 비표면적강저0.9m2/g,진실밀도종0.95g/cm3제고지1.08g/cm3;불가역용량손실종121mAh/g감소도44mAh/g,가역용량종300mAh/g 제고도320mAh/g,수차고륜효솔종71.2%제고도87.4%,이차순배성능득도명현개선。
To address the shortcomings,such as low tap density and low first cycle Coulombic efficiency of mi-crocrystalline graphite when used as lithium ion battery anode,the paper investigated the liquid phase coating for microcrystalline graphite using vacuum impregnation method.The microscopic structure of the coated sam-ple was tested with XRD,Raman spectrum.The surface feature was characterized by SEM and nitrogen ad-sorption-desorption.The performance of the sample was determined by galvanostatic test and CV test.It shows that after the modification,the degree of graphitization was reduced slightly,the Raman R value increases from 0.63 to 0.85,the surface of the graphite particles become neater and smoother,the BET specific surface area decreases by 0.9m2/g,and the tap density increases from 0.95 to 1.08g/m3 .The electrochemical performance of the modified graphite was significantly improved.and the irreversible capacity was reduced from 1 2 1 to 44mAh/g.The reversible capacity increases from 300 to 320mAh/g,the initial Coulombic efficiency increases from 71.2% to 87.4%.The cycle stability was improved significantly.