石油化工高等学校学报
石油化工高等學校學報
석유화공고등학교학보
JOURNAL OF PETROCHEMICAL UNIVERSITIES
2013年
4期
62-65,82
,共5页
含氟表面活性剂%接触角%石英表面%驱油效率
含氟錶麵活性劑%接觸角%石英錶麵%驅油效率
함불표면활성제%접촉각%석영표면%구유효솔
Fluoro-surfactant%Contact angle%Quartz surface%Oil displacement efficiency
利用座滴法研究了含氟表面活性剂在石英表面形成的吸附膜的润湿性质,考察了温度及不同类型电解质对其接触角的影响趋势,并开展了室内模拟驱油实验。研究发现,两性含氟表面活性剂可以有效地改变石英表面的润湿性,在蒸馏水及模拟地层水的条件下都可以使亲水的石英表面变为中性。同时,两性含氟表面活性剂具有较好的抗盐性及耐温性。室内模拟驱油实验显示,两性含氟表面活性剂将岩心的润湿性控制在中性弱亲水状态,促进孔道水膜剥离,减小水驱渗流阻力,从而降低水驱压力和提高原油采收率。
利用座滴法研究瞭含氟錶麵活性劑在石英錶麵形成的吸附膜的潤濕性質,攷察瞭溫度及不同類型電解質對其接觸角的影響趨勢,併開展瞭室內模擬驅油實驗。研究髮現,兩性含氟錶麵活性劑可以有效地改變石英錶麵的潤濕性,在蒸餾水及模擬地層水的條件下都可以使親水的石英錶麵變為中性。同時,兩性含氟錶麵活性劑具有較好的抗鹽性及耐溫性。室內模擬驅油實驗顯示,兩性含氟錶麵活性劑將巖心的潤濕性控製在中性弱親水狀態,促進孔道水膜剝離,減小水驅滲流阻力,從而降低水驅壓力和提高原油採收率。
이용좌적법연구료함불표면활성제재석영표면형성적흡부막적윤습성질,고찰료온도급불동류형전해질대기접촉각적영향추세,병개전료실내모의구유실험。연구발현,량성함불표면활성제가이유효지개변석영표면적윤습성,재증류수급모의지층수적조건하도가이사친수적석영표면변위중성。동시,량성함불표면활성제구유교호적항염성급내온성。실내모의구유실험현시,량성함불표면활성제장암심적윤습성공제재중성약친수상태,촉진공도수막박리,감소수구삼류조력,종이강저수구압력화제고원유채수솔。
The wetting properties of quartz surface modified by adsorption films of fluoro-surfactants were investigated using the sessile drop analysis .The influences of temperature and different electrolytes were expounded and laboratory simulation of displacement testing was carried out . The results show that zwitterionic fluoro-surfactant FO1 will effectively alter the wettability of quartz surface .FO1 can both modify the quartz surface from hydrophilic surface to neutral one in distilled water and formation water .Meanwhile ,FO1 shows better heat resistance and salt tolerance .The result of laboratory simulation of displacement experiment show that the core surface is controlled in slightly water-wetting by zwitterionic fluoro-surfactan solutions ,which is beneficial to the removing of the water film from core surface and reducing the percolation resistance of water flooding ,and results in decrease of water injection pressure and enhancement of the oil recovery .