检验检疫学刊
檢驗檢疫學刊
검험검역학간
INSPECTION AND QUARANTINE SCIENCE
2013年
4期
29-31
,共3页
刘益锋%田琼%杨树洁%吕善胜%林海%刘中勇
劉益鋒%田瓊%楊樹潔%呂善勝%林海%劉中勇
류익봉%전경%양수길%려선성%림해%류중용
X射线荧光光谱法%多元素测定%重晶石
X射線熒光光譜法%多元素測定%重晶石
X사선형광광보법%다원소측정%중정석
X-Ray Fluorescence Spectrometry%Determination of Multi-Elements%Baryte
采用偏硼酸锂和四硼酸锂混合熔剂熔融法制样,波长色散X射线荧光光谱法测定重晶石中钡、锶、铁、铝、硅。采用理论α系数和经验系数相结合的方法校正元素间的基体效应。测定重晶石试样各组分的相对标准偏差(RSD,n=12)均小于5.5%,结果与化学分析法吻合。
採用偏硼痠鋰和四硼痠鋰混閤鎔劑鎔融法製樣,波長色散X射線熒光光譜法測定重晶石中鋇、鍶、鐵、鋁、硅。採用理論α繫數和經驗繫數相結閤的方法校正元素間的基體效應。測定重晶石試樣各組分的相對標準偏差(RSD,n=12)均小于5.5%,結果與化學分析法吻閤。
채용편붕산리화사붕산리혼합용제용융법제양,파장색산X사선형광광보법측정중정석중패、송、철、려、규。채용이론α계수화경험계수상결합적방법교정원소간적기체효응。측정중정석시양각조분적상대표준편차(RSD,n=12)균소우5.5%,결과여화학분석법문합。
A method has been developed for direct determination of Ba, Sr, Fe, Al and Si elements in baryte samples using fusion method by Axios PW4400 XRF spectrometer. The matrix effect was corrected by theoretical alpha coefficients and empirical coefficients. The precision (RSD, n=12) of the method is less than 5.5%for major elements and other elements.