CAJ | 학술논문

采用密闭高压消解法对样品进行消解，用电感耦合等离子体发射光谱法（ICP-AES）测定进口铜精矿中的铅、镉、砷、汞有害元素。铅、镉、砷、汞的工作曲线分别在0～10，0～1，0～4，0～0.6μg/mL范围内线性良好，线性相关系数大于0.999。各元素加标回收率均为91.0%～104.7%，相对标准偏差均小于3%（n=7）。将密闭高压消解法与电热板加热法和微波消解法进行了比对分析，结果显示，密闭高压消解-ICP-AES法适合用于铜精矿样品的消解与测定。
채용밀폐고압소해법대양품진행소해，용전감우합등리자체발사광보법（ICP-AES）측정진구동정광중적연、력、신、홍유해원소。연、력、신、홍적공작곡선분별재0～10，0～1，0～4，0～0.6μg/mL범위내선성량호，선성상관계수대우0.999。각원소가표회수솔균위91.0%～104.7%，상대표준편차균소우3%（n=7）。장밀폐고압소해법여전열판가열법화미파소해법진행료비대분석，결과현시，밀폐고압소해-ICP-AES법괄합용우동정광양품적소해여측정。
The method of determination of lead, cadmium, mercury and arsenic in copper concentrates for import by ICP-AES with sealed high pressure digestion for the sample was established. The linear range of lead, cadmium, mercury,arsenic was 0-10,0-1,0-4,0-0.6μg/mL respectively with the correlation coefficient more than 0.999. The elements recoveries ranged from 91.0%to 104.7%,and the relative standard deviation was less than 3%(n=7). The sealed high pressure digestion method was compared with the heating plates method and the microwave digestion method. The results showed that sealed high pressure digestion was effective for the digestion of copper concentrate samples.