含能材料
含能材料
함능재료
ENERGETIC MATERIALS
2013年
5期
684-687
,共4页
李怡%李兆乾%黄洪驰%裴重华
李怡%李兆乾%黃洪馳%裴重華
리이%리조건%황홍치%배중화
材料科学%硝化棉%抗静电性能%导电填料%薄膜%复合材料
材料科學%硝化棉%抗靜電性能%導電填料%薄膜%複閤材料
재료과학%초화면%항정전성능%도전전료%박막%복합재료
materials science%nitrocellulose%antistatic performance%conductive filler%membrane%composite materials
以硝化棉作为原料,选择碳系导电填料,通过液相共混复合法,制备了抗静电硝化棉薄膜。用高阻计和静电感度测试仪、电子万能试验机及场发射扫描电子显微镜分别表征了抗静电硝化棉薄膜的抗静电性能、力学性能以及微观形貌。结果表明,当添加1%的碳系导电填料时,抗静电硝化棉薄膜的表面电阻率和体积电阻率分别为:2.2×109Ω和7.5×109Ω· m,相比纯硝化棉,分别降低了6个数量级和3个数量级。其静电火花感度为2.31 J,相比纯硝化棉,增大了14%,显示最佳抗静电性能。力学性能参数有所提高,说明导电填料的加入,不会削弱硝化棉本身的力学性能。制品内部形成的均匀导电网络会使静电荷消散。
以硝化棉作為原料,選擇碳繫導電填料,通過液相共混複閤法,製備瞭抗靜電硝化棉薄膜。用高阻計和靜電感度測試儀、電子萬能試驗機及場髮射掃描電子顯微鏡分彆錶徵瞭抗靜電硝化棉薄膜的抗靜電性能、力學性能以及微觀形貌。結果錶明,噹添加1%的碳繫導電填料時,抗靜電硝化棉薄膜的錶麵電阻率和體積電阻率分彆為:2.2×109Ω和7.5×109Ω· m,相比純硝化棉,分彆降低瞭6箇數量級和3箇數量級。其靜電火花感度為2.31 J,相比純硝化棉,增大瞭14%,顯示最佳抗靜電性能。力學性能參數有所提高,說明導電填料的加入,不會削弱硝化棉本身的力學性能。製品內部形成的均勻導電網絡會使靜電荷消散。
이초화면작위원료,선택탄계도전전료,통과액상공혼복합법,제비료항정전초화면박막。용고조계화정전감도측시의、전자만능시험궤급장발사소묘전자현미경분별표정료항정전초화면박막적항정전성능、역학성능이급미관형모。결과표명,당첨가1%적탄계도전전료시,항정전초화면박막적표면전조솔화체적전조솔분별위:2.2×109Ω화7.5×109Ω· m,상비순초화면,분별강저료6개수량급화3개수량급。기정전화화감도위2.31 J,상비순초화면,증대료14%,현시최가항정전성능。역학성능삼수유소제고,설명도전전료적가입,불회삭약초화면본신적역학성능。제품내부형성적균균도전망락회사정전하소산。
A kind of antistatic nitrocellulose ( NC) membrane was successfully prepared via the liquid phase mixing complex meth-od using NC as raw materials and selecting carbon series conductive filler to NC.The antistatic performance, mechanical property and microstructure of antistatic NC membrane were characterized by high resistance meter, static sensitivity tester, electronic uni-versal testing machine and field emission scanning electron microscope, respectively.The results show that when 1.0% conduc-tive filler is added, the surface resistivity and volume resistivity of the antistatic NC membrane are 2.2 ×109Ωand 7.5 ×109Ω· m. respectively.Compared with unmodified NC, the surface resistivity and volume resistivity of the antistatic NC membrane are re-duced by 6 orders of magnitude and 3 orders of magnitude, respectively.The electrostatic spark sensitivity of the antistatic NC membrane is 2.31 J.Compared with unmodified NC the electrostatic spark sensitivity of the antistatic NC membrane is increased by 14%, revealing that the antistatic NC membrane has better antistatic performance.The mechanical property parameters of the antistatic NC membrane are improved, showing that the addition of conductive filler does not degrade the mechanical property of NC .The formation of interlaced conductive networks in the products is conduciue to the electrostatic charge dissipate.