含能材料
含能材料
함능재료
ENERGETIC MATERIALS
2013年
5期
664-667
,共4页
李学军%丛晓民%杜志明%赵家玉
李學軍%叢曉民%杜誌明%趙傢玉
리학군%총효민%두지명%조가옥
军事化学与烟火技术%烟火学%稀土元素%燃烧光谱
軍事化學與煙火技術%煙火學%稀土元素%燃燒光譜
군사화학여연화기술%연화학%희토원소%연소광보
military chemistry and protechnics%pyrotechnics%rare earth%combustion spectra
为探究稀土元素用于发光类烟火药剂的可能性,以稀土硝酸盐为氧化剂、镁粉为可燃剂、淀粉为粘合剂,设计、制备了含Ce、Pr、Sm、Eu、Tb、Dy、Yb 7种稀土元素的烟火药剂。用瞬态分光辐射仪测定了各药剂的燃烧光谱。分析了各药剂的光谱分布。结果表明:药剂的负氧氧平衡越高,特征光谱辐射强度越大。含不同稀土元素药剂的特征辐射光谱分布区间有相似性。含Eu元素药剂的光谱辐射分布在红光区。
為探究稀土元素用于髮光類煙火藥劑的可能性,以稀土硝痠鹽為氧化劑、鎂粉為可燃劑、澱粉為粘閤劑,設計、製備瞭含Ce、Pr、Sm、Eu、Tb、Dy、Yb 7種稀土元素的煙火藥劑。用瞬態分光輻射儀測定瞭各藥劑的燃燒光譜。分析瞭各藥劑的光譜分佈。結果錶明:藥劑的負氧氧平衡越高,特徵光譜輻射彊度越大。含不同稀土元素藥劑的特徵輻射光譜分佈區間有相似性。含Eu元素藥劑的光譜輻射分佈在紅光區。
위탐구희토원소용우발광류연화약제적가능성,이희토초산염위양화제、미분위가연제、정분위점합제,설계、제비료함Ce、Pr、Sm、Eu、Tb、Dy、Yb 7충희토원소적연화약제。용순태분광복사의측정료각약제적연소광보。분석료각약제적광보분포。결과표명:약제적부양양평형월고,특정광보복사강도월대。함불동희토원소약제적특정복사광보분포구간유상사성。함Eu원소약제적광보복사분포재홍광구。
In order to explore the possibility of rare-earth elements usage in luminescent pyrotechnics, magnesium powder as com-bustion agent and starch as binder, seven kinds of pyrotechnic composites containing Ce, Pr, Sm, Eu, Tb, Dy and Yb as oxidants were designed and prepared.The combustion spectra of each pyrotechnic composite were recorded by a transient spectral radiom-eter.Their spectral distributions were analyzed.Results show that the higher the negative oxygen balance of pyrotechnic compos-ites, the greater the radiation intensity of characteristic spectum.The characteristic radiation spectra distribution region of pyrotech-nic composites containing different rare-earth elements is similar.The spectral radiation of pyrotechnic composites containing Eu distributes in red light region.