CAJ | 학술논문

用2，4，6-三氨基-3，5-二硝基吡啶-1-氧化物（TANPyO）作配体，合成了两种过渡金属[Ni（Ⅱ）和Cu（Ⅱ）]配合物，并用红外、元素分析、DSC、TG-DTG 进行了表征。研究了两种配合物对高氯酸铵（AP）热分解的影响。按 GJB772A -1997测试了TANPyO的感度。结果表明，配合物的热分解过程仅由1个剧烈放热峰组成，剩余残渣为金属氧化物。两种配合物使AP高温分解峰温度分别提前47．14℃和98．24℃，分解速度加快，放热量增加，显示这两种配合物对AP热分解有良好的催化效果。撞击落高为300 cm，摩擦感度和静电火花感度均为0，表明TANPyO是一种非常钝感的含能材料。
용2，4，6-삼안기-3，5-이초기필정-1-양화물（TANPyO）작배체，합성료량충과도금속[Ni（Ⅱ）화Cu（Ⅱ）]배합물，병용홍외、원소분석、DSC、TG-DTG 진행료표정。연구료량충배합물대고록산안（AP）열분해적영향。안 GJB772A -1997측시료TANPyO적감도。결과표명，배합물적열분해과정부유1개극렬방열봉조성，잉여잔사위금속양화물。량충배합물사AP고온분해봉온도분별제전47．14℃화98．24℃，분해속도가쾌，방열량증가，현시저량충배합물대AP열분해유량호적최화효과。당격락고위300 cm，마찰감도화정전화화감도균위0，표명TANPyO시일충비상둔감적함능재료。
Two transition metal (Ni(Ⅱ) and Cu(Ⅱ)) complexes were synthesized using 2, 4, 6-triamino-3, 5-dinitropyridine-1-oxide ( TANPyO) as ligand and characterized by FT-IR spectroscopy, elemental analysis, DSC and TG-DTG.Effects of the two complexes on the thermal decomposition of ammonium perchlorate ( AP) were studied.The sensitivity properties of TANPyO were tested according to specifications of standardization method GJB772A-1997.Results show that the thermal decomposition proces-ses of two complexes both consist of one violent exothermic peak with metal oxides residues.The two complexes make the higher thermal decomposition temperature of AP decrease by 47.14℃and 98.24℃, the decomposition reaction accelerate and the exo-thermic quantity increase, revealing that the two complexes have good catalytic effect on the thermal decomposition of AP.The drop height of impact sensitivity is 300 cm.The friction sensitivity and electrostatic spark sensitivity are zero, showing that TANPyO is an insensitive energetic compound.