化学研究与应用
化學研究與應用
화학연구여응용
CHEMICAL RESEARCH AND APPLICATION
2013年
8期
1136-1139
,共4页
罗健辉%张雨露%杨博文%叶龙强%丁彬%江波
囉健輝%張雨露%楊博文%葉龍彊%丁彬%江波
라건휘%장우로%양박문%협룡강%정빈%강파
SiO2 纳米微粒%溶胶-凝胶技术%六甲基二硅氮烷%可湿性%油层采收率
SiO2 納米微粒%溶膠-凝膠技術%六甲基二硅氮烷%可濕性%油層採收率
SiO2 납미미립%용효-응효기술%륙갑기이규담완%가습성%유층채수솔
silica nanoparticles%sol-gel technology%HMDS%wettability%oil recovery
本文利用溶胶-凝胶( sol-gel)技术并在St?ber法的基础上,制备了粒径尺寸在20 nm到90 nm可控的SiO2纳米微粒。通过控制氨水的起始浓度可较为便捷的调控粒子的尺寸。六甲基二硅氮烷( HMDS)用做疏水改性剂,以调整纳米微粒的润湿性。改性粒子的红外光谱亦证明了HMDS的成功引入。这些疏水亲油的纳米微粒可望用于纳米液中,以增大注水量并最终提高油层采收率。
本文利用溶膠-凝膠( sol-gel)技術併在St?ber法的基礎上,製備瞭粒徑呎吋在20 nm到90 nm可控的SiO2納米微粒。通過控製氨水的起始濃度可較為便捷的調控粒子的呎吋。六甲基二硅氮烷( HMDS)用做疏水改性劑,以調整納米微粒的潤濕性。改性粒子的紅外光譜亦證明瞭HMDS的成功引入。這些疏水親油的納米微粒可望用于納米液中,以增大註水量併最終提高油層採收率。
본문이용용효-응효( sol-gel)기술병재St?ber법적기출상,제비료립경척촌재20 nm도90 nm가공적SiO2납미미립。통과공제안수적기시농도가교위편첩적조공입자적척촌。륙갑기이규담완( HMDS)용주소수개성제,이조정납미미립적윤습성。개성입자적홍외광보역증명료HMDS적성공인입。저사소수친유적납미미립가망용우납미액중,이증대주수량병최종제고유층채수솔。
Silica nanoparticles with particle size ranged from about 20 nm to 90 nm were prepared by sol-gel technology based on St?ber method.The particle size could be controlled conveniently by varying the initial concentration of ammo -nia.Hexamethyldisilazane ( HMDS) was used to modify the wettability of these silica nanoparticles and FTIR spectral demonstrated that HMDS was successfully introduced in the surface of silica particles.The obtained hydrophobic and lipophilic nanoparticles are expected for the use of nanofluids ,which could improve the water injection and therefore enhance oil recovery.