CAJ | 학술논문

以水杨醛与3，5-二氨基苯甲酸为原料，通过醛胺缩合制成席夫碱配体，并与Co2+、Mn2+、Cu2+金属离子络合得到了相应的过渡金属配合物，采用紫外光谱、红外光谱、1H-NMR对其结构进行了表征。并将这3种席夫碱金属配合物作为催化剂用于棉针织物双氧水低温漂白，测试并比较了催化剂种类、配合物浓度、双氧水浓度、pH值、温度和时间对漂白效果的影响。结果表明，3种催化剂都具有低温催化漂白性能，其中Mn2L的催化漂白效果最好；最佳漂白工艺：30% H2O2为10 g/L，Mn2L为20μmol/L，pH值为11， Na2SiO3为1 g/L，JFC为1 g/L，70℃处理60 min，浴比1∶20。
이수양철여3，5-이안기분갑산위원료，통과철알축합제성석부감배체，병여Co2+、Mn2+、Cu2+금속리자락합득도료상응적과도금속배합물，채용자외광보、홍외광보、1H-NMR대기결구진행료표정。병장저3충석부감금속배합물작위최화제용우면침직물쌍양수저온표백，측시병비교료최화제충류、배합물농도、쌍양수농도、pH치、온도화시간대표백효과적영향。결과표명，3충최화제도구유저온최화표백성능，기중Mn2L적최화표백효과최호；최가표백공예：30% H2O2위10 g/L，Mn2L위20μmol/L，pH치위11， Na2SiO3위1 g/L，JFC위1 g/L，70℃처리60 min，욕비1∶20。
With salicylaldehyde and 3,5-diaminobenzoic acid as raw materials, schiff-base ligand was made through condensation of aldehyde and amine, and transition-metals complex was obtained by complexing with schiff-base ligand and Co2+,Mn2+,Cu2+. Its construction was represented by UV-vis, IR and 1H-NMR, and the three kinds of Schiff base metal complexes were applied on hydrogen peroxide bleaching at low temperature for cotton knitted fabric as catalyst. The effects of catalyst type, the concentration of complex and hydrogen peroxide, pH val-ue, temperature and time on bleaching effect were tested and compared. The results show that these three kinds of catalyst all have the property of bleaching at low temperature, and the bleaching property of Mn2L is the best; the optimal bleaching process is listed respectively: 30% H2O2 is 10 g/L, Mn2L is 20 μmol/L, Na2SiO3 is 1 g/L, JFC is 1 g/L, pH value is 11 at 70 ℃ for 60 minutes and bath ratio is 1∶20.