CAJ | 학술논문

建立胶束电动色谱在线推扫富集法检测蔬菜中残留的痕量福利多。讨论了十二烷基硫酸钠（SDS）浓度、NaH2PO4浓度、缓冲液pH、有机溶剂添加量、样品中电解质浓度、运行电压、进样压力对富集效果的影响；考察了活性炭净化对回收率的影响。结果：选择20 mmol/L磷酸二氢钠+120 mmol/LSDS（pH=6.2），甲醇30%（体积比）为缓冲液，电压7 kV，进样压力2406.25 kPa×s。1.8 g活性炭的加入对回收率没有明显的影响。福利多在0.06 mg/L～2 mg/L范围内线性关系良好，相关系数为0.9989，检测限为0.038 mg/L。加标水平在0.32 mg/kg～0.48 mg/kg范围内，回收率为90.30%～90.52%，相对标准偏差（RSD）为1.01%～1.44%（n=3）。胶束电动色谱在线推扫富集法可用于蔬菜中残留痕量农药的检测。
건립효속전동색보재선추소부집법검측소채중잔류적흔량복리다。토론료십이완기류산납（SDS）농도、NaH2PO4농도、완충액pH、유궤용제첨가량、양품중전해질농도、운행전압、진양압력대부집효과적영향；고찰료활성탄정화대회수솔적영향。결과：선택20 mmol/L린산이경납+120 mmol/LSDS（pH=6.2），갑순30%（체적비）위완충액，전압7 kV，진양압력2406.25 kPa×s。1.8 g활성탄적가입대회수솔몰유명현적영향。복리다재0.06 mg/L～2 mg/L범위내선성관계량호，상관계수위0.9989，검측한위0.038 mg/L。가표수평재0.32 mg/kg～0.48 mg/kg범위내，회수솔위90.30%～90.52%，상대표준편차（RSD）위1.01%～1.44%（n=3）。효속전동색보재선추소부집법가용우소채중잔류흔량농약적검측。
A micellar electrokinetic chromatography (MEKC)sweeping technique was developed for the determi-nation of folidol in vegetables.The effects of the concentration of SDS, the concentration of NaH2PO4, the pH of running buffer,the concentration of organic additive,the concentration of solution to dilute sample, voltage and injection pressure on enrichment effect were discussed.The effect of additiving the activated carbon to sample on recovery was discussed. 20 mmol/L NaH2PO4+120 mmol/L SDS(pH 6.2),Methanol 30%(volume ratio) was used as running buffer,the voltage was 7 kV,the injection pressure was 2 406.25 kPa ×s.The recovery was not effected by 1.8 g activated carbon adding to the vegetable.The calibration curves had good linearity in the range of 0.06 mg/L-2 mg/L for folidol,the correlation coefficients was 0.998 9,the detection limit was 0.038 mg/L. At spikedlevels of 0.32 mg/kg-0.48 mg/kg,the recoveries were 90.30 %-90.52 %,the relative standard deviations was 1.01%-1.44%(n=4).The MEKC method based on on-line Sweeping technique can be used to detect the residuals of trace pesticides in vegetables.