工程塑料应用
工程塑料應用
공정소료응용
ENGINEERING PLASTICS APPLICATION
2013年
7期
92-95
,共4页
张玉坤%沈鹏%王希%杨昌玉%梁基照
張玉坤%瀋鵬%王希%楊昌玉%樑基照
장옥곤%침붕%왕희%양창옥%량기조
聚偏氟乙烯%聚乙二醇%分离膜%结晶性%亲水性
聚偏氟乙烯%聚乙二醇%分離膜%結晶性%親水性
취편불을희%취을이순%분리막%결정성%친수성
poly(vinylidene fluoride)%polyethylene glycol%separation membrane%crystalline%hydrophilicity
以聚乙二醇(PEG)为添加剂,利用非溶剂致相分离法制备了聚偏氟乙烯(PVDF)/PEG共混膜,使用傅里叶变换红外光谱、X射线衍射、扫描电子显微镜、接触角测量等表征测试方法,研究了PEG含量对PVDF/PEG共混膜性能的影响。结果发现,PEG的加入使PVDF的结晶性能下降,同时也使其结构发生了变化。但是由于PEG的亲水性,当PEG的质量分数小于5%时,PVDF/PEG共混膜的亲水性随着PEG含量的增大而逐渐得到改善。
以聚乙二醇(PEG)為添加劑,利用非溶劑緻相分離法製備瞭聚偏氟乙烯(PVDF)/PEG共混膜,使用傅裏葉變換紅外光譜、X射線衍射、掃描電子顯微鏡、接觸角測量等錶徵測試方法,研究瞭PEG含量對PVDF/PEG共混膜性能的影響。結果髮現,PEG的加入使PVDF的結晶性能下降,同時也使其結構髮生瞭變化。但是由于PEG的親水性,噹PEG的質量分數小于5%時,PVDF/PEG共混膜的親水性隨著PEG含量的增大而逐漸得到改善。
이취을이순(PEG)위첨가제,이용비용제치상분리법제비료취편불을희(PVDF)/PEG공혼막,사용부리협변환홍외광보、X사선연사、소묘전자현미경、접촉각측량등표정측시방법,연구료PEG함량대PVDF/PEG공혼막성능적영향。결과발현,PEG적가입사PVDF적결정성능하강,동시야사기결구발생료변화。단시유우PEG적친수성,당PEG적질량분수소우5%시,PVDF/PEG공혼막적친수성수착PEG함량적증대이축점득도개선。
Poly(vinylidene fluoride) (PVDF) separation membranes were prepared through non-solvent induced phase separation method,with polyethylene glycol(PEG) as additive.Then influence of PEG content on the properties of PVDF/PEG membranes was studied with the help of some characterization methods,such as FTIR,XRD,SEM,CA.The results show that the addition of PEG inhibits the crystallization of PVDF,and also changes the micro structure of PVDF.However.Owing to the hydrophilicity of PEG,hydrophilicity of PVDF/PEG membranes gradually is improved with the increase of PEG content,when the content of PEG is less than 5%.