岩矿测试
巖礦測試
암광측시
ROCK AND MINERAL ANALYSIS
2014年
3期
332-339
,共8页
王艳蓉%朱铁权%冯泽阳%谭羡%叶道阳%郑颖
王豔蓉%硃鐵權%馮澤暘%譚羨%葉道暘%鄭穎
왕염용%주철권%풍택양%담이%협도양%정영
南海Ⅰ号%古陶瓷%青白瓷%青瓷%绿釉陶%科技分析
南海Ⅰ號%古陶瓷%青白瓷%青瓷%綠釉陶%科技分析
남해Ⅰ호%고도자%청백자%청자%록유도%과기분석
Nanhai No. 1 Shipwreck%ancient ceramics%bluish-white porcelain%celadon%green glazed pottery%technological analysis
“南海Ⅰ号”沉船位于我国广东省阳江市，出水大量陶瓷器的产地研究及腐蚀产物研究是“南海Ⅰ号”研究的重要课题。本文利用微聚焦X射线荧光光谱仪（μ-XRF）对“南海Ⅰ号”沉船出水部分的青白瓷、青瓷、绿釉陶的胎釉以及绿釉陶的腐蚀物进行成分分析，并利用体视显微镜以及拉曼光谱仪对绿釉陶表面的腐蚀物进行观察和物相组成分析。元素分析结果表明：一类青白瓷样品胎体具有低铝高硅的特点（ Al2 O3含量低于19%，SiO2含量约73%），属江西景德镇湖田窑，而另一类青白瓷可能产自福建，具体窑口的确定还有待进一步对比分析才能得出明确的结论；青瓷样品胎体具有高硅低铝的特点（ Al2 O3含量13.32%~19.12%；SiO2含量72.89%~78.30%），属浙江龙泉窑；绿釉陶样品的特征与福建地区瓷土较为符合，可能来自于福建磁灶窑。拉曼光谱物相分析结果表明，绿釉陶的主要腐蚀物的矿物组成为炭黑、白铅矿与磷酸铅。此项研究成果为出水陶瓷器的产地研究、陶瓷器腐蚀机理探究、出水陶瓷器保护等提供了重要依据。
“南海Ⅰ號”沉船位于我國廣東省暘江市，齣水大量陶瓷器的產地研究及腐蝕產物研究是“南海Ⅰ號”研究的重要課題。本文利用微聚焦X射線熒光光譜儀（μ-XRF）對“南海Ⅰ號”沉船齣水部分的青白瓷、青瓷、綠釉陶的胎釉以及綠釉陶的腐蝕物進行成分分析，併利用體視顯微鏡以及拉曼光譜儀對綠釉陶錶麵的腐蝕物進行觀察和物相組成分析。元素分析結果錶明：一類青白瓷樣品胎體具有低鋁高硅的特點（ Al2 O3含量低于19%，SiO2含量約73%），屬江西景德鎮湖田窯，而另一類青白瓷可能產自福建，具體窯口的確定還有待進一步對比分析纔能得齣明確的結論；青瓷樣品胎體具有高硅低鋁的特點（ Al2 O3含量13.32%~19.12%；SiO2含量72.89%~78.30%），屬浙江龍泉窯；綠釉陶樣品的特徵與福建地區瓷土較為符閤，可能來自于福建磁竈窯。拉曼光譜物相分析結果錶明，綠釉陶的主要腐蝕物的礦物組成為炭黑、白鉛礦與燐痠鉛。此項研究成果為齣水陶瓷器的產地研究、陶瓷器腐蝕機理探究、齣水陶瓷器保護等提供瞭重要依據。
“남해Ⅰ호”침선위우아국광동성양강시，출수대량도자기적산지연구급부식산물연구시“남해Ⅰ호”연구적중요과제。본문이용미취초X사선형광광보의（μ-XRF）대“남해Ⅰ호”침선출수부분적청백자、청자、록유도적태유이급록유도적부식물진행성분분석，병이용체시현미경이급랍만광보의대록유도표면적부식물진행관찰화물상조성분석。원소분석결과표명：일류청백자양품태체구유저려고규적특점（ Al2 O3함량저우19%，SiO2함량약73%），속강서경덕진호전요，이령일류청백자가능산자복건，구체요구적학정환유대진일보대비분석재능득출명학적결론；청자양품태체구유고규저려적특점（ Al2 O3함량13.32%~19.12%；SiO2함량72.89%~78.30%），속절강룡천요；록유도양품적특정여복건지구자토교위부합，가능래자우복건자조요。랍만광보물상분석결과표명，록유도적주요부식물적광물조성위탄흑、백연광여린산연。차항연구성과위출수도자기적산지연구、도자기부식궤리탐구、출수도자기보호등제공료중요의거。
‘Nanhai No. 1 Shipwreck’was discovered in Yangjiang City,Guangdong Province. Research on the origins of these out-water ceramics and corrosion products of ceramics play an important role. The component analysis of body and glaze of bluish-white porcelains,celadons,green glazed potteries and the corrosion products specimens of green glazed potteries have been studied by using Micro-focus X-ray Fluorescence Spectrometer(μ-XRF). Then,the observation and phase analysis of corrosion products specimens of green glazed potteries were conducted by using Stereo Microscope (OM)and Raman Spectroscopy(μ-RS). Combined with ceramic archaeological literature,it ws found that:(1)some bluish-white porcelains are characterized by low content of aluminum and high content of silicon( content of Al2 O3 is less than 19%,content of SiO2 is almost 73%),which come from Jingdezhen Hutian kiln;another bluish-white porcelain may be from Fujian Province,which needs further support evidence.(2)The celadons all have a high content of silicon and low content of aluminum( Al2 O3:13. 32% -19. 12%;SiO2:72. 89% -78. 30%),which come from Zhejiang Longquan kiln;additionally,some celadons belong to lime glaze which possess more similar characteristics to Longquan kiln of the Northern Song Dynasty;some belong to lime alkaline glaze which possess similar characteristics to Longquan kiln of Southern Song Dynasty.(3)Green glazed pottery samples possess more similar characteristics to the Fujian area, which may come from Fujian CiZao kiln ;in order to have in - depth research on corrosion products of green glazed potteries,representative samples are selected to have Raman spectroscopy analysis;the main compositions are black carbon,cerusite and lead phosphate. In this work,technology analysis has been carried out with some underwater ceramic of‘Nanhai No. 1 Shipwreck’to identify some origins of ceramics. The results of this study provide an important basis for the study of the origin of the out-water ceramics,corrosion mechanism of ceramics,ceramic water protection of out-water ceramics amongst other aspects of ceramic origin determination.
