全面腐蚀控制
全麵腐蝕控製
전면부식공제
TOTAL CORROSION CONTROL
2013年
9期
56-60
,共5页
7075-T6镁铝合金%自腐蚀电位%极化曲线%电化学阻抗谱%生物膜%微生物腐蚀
7075-T6鎂鋁閤金%自腐蝕電位%極化麯線%電化學阻抗譜%生物膜%微生物腐蝕
7075-T6미려합금%자부식전위%겁화곡선%전화학조항보%생물막%미생물부식
7075-T6 magnesium aluminum alloy%corrosion potential%polarization curves%electrochemical impedance spectra%biofilm%microorganism corrosion
采用电化学方法研究了7075-T6镁铝合金在含有微生物的航煤溶液中的腐蚀行为。结果表明:微生物的存在使得镁铝合金的自腐蚀电位时而正移时而负移,溶液中的pH值下降,合金的耐蚀性降低;浸泡前期,电极表面形成的生物膜均匀致密,可以减缓基体的腐蚀;浸泡后期,生物膜破裂,加速了阴极去极化作用,基体腐蚀加速;生物膜的不断生成和破裂,使得溶液中的离子及溶解氧扩散到电极表面,导致腐蚀持续加速进行。
採用電化學方法研究瞭7075-T6鎂鋁閤金在含有微生物的航煤溶液中的腐蝕行為。結果錶明:微生物的存在使得鎂鋁閤金的自腐蝕電位時而正移時而負移,溶液中的pH值下降,閤金的耐蝕性降低;浸泡前期,電極錶麵形成的生物膜均勻緻密,可以減緩基體的腐蝕;浸泡後期,生物膜破裂,加速瞭陰極去極化作用,基體腐蝕加速;生物膜的不斷生成和破裂,使得溶液中的離子及溶解氧擴散到電極錶麵,導緻腐蝕持續加速進行。
채용전화학방법연구료7075-T6미려합금재함유미생물적항매용액중적부식행위。결과표명:미생물적존재사득미려합금적자부식전위시이정이시이부이,용액중적pH치하강,합금적내식성강저;침포전기,전겁표면형성적생물막균균치밀,가이감완기체적부식;침포후기,생물막파렬,가속료음겁거겁화작용,기체부식가속;생물막적불단생성화파렬,사득용액중적리자급용해양확산도전겁표면,도치부식지속가속진행。
The corrosion behaviors of 7075-T6 magnesium aluminum alloy in aviation kerosene solution with microorganisms were studied by corrosion potential, electrochemical impedance spectra, polarization curves, etc. Results show that the presence of microorganisms make the corrosion potential of magnesium aluminum alloy sometimes positive shift and sometimes negative shift , the pH value of solution decline, the decrease of magnesium aluminum alloy‘s corrosion resistance. At the early stage of the soak, the biofilm formed on the electrode surface is uniform and dense, which can slow down the corrosion of the matrix. Later, the biofilm rupture and accelerate the cathodic depolarization and the corrosion rate of the matrix. Continuous formation and rupture of biofilm, making the ions and dissolved oxygen of the solution diffuse to the electrode surface, causing corrosion sustained acceleration.