稀土学报(英文版)
稀土學報(英文版)
희토학보(영문판)
JOURNAL OF RARE EARTHS
2013年
10期
1017-1022
,共6页
丁玉石%厉英%邓文卓%黄文龙%王常珍
丁玉石%厲英%鄧文卓%黃文龍%王常珍
정옥석%려영%산문탁%황문룡%왕상진
BaZr1-xYxO3-α%proton conductors%conductivity%optimum doping concentration%EIS%rare earths
A solid state reaction method was used to prepare the perovskite-structured compounds BaZr1-xYxO3-α(x=0, 0.05, 0.1, 0.15, 0.2, 0.25, 0.3). The X-ray diffraction (XRD) pattern indicated that the target perovskite phases were obtained. With increasing Y con-centration the unit cell parameters of BaZr1-xYxO3-αsamples were expanded, and Y doping became more difficult. However, high synthesis temperature is helpful to promote Y doping. The SEM results showed that the samples exhibited poor sinterability with in-creasing Y-doping content. Thermal gravimetric (TG) curves analysis showed the more mass decreasing of BaZr1-xYxO3-α(0≤x≤0.3) samples at high temperature with more Y doping and more proton introducing. The electrochemical impedance spectra (EIS) of specimens showed that conductivities of BaZr1-xYxO3-α(0≤x≤0.3) increased with increasing temperature from 300 to 900 °C in wet air. At 900 °C, the conductivity of BaZr1-xYxO3-α(0≤x≤0.3) first increased with increasing doped amount of Y, and reached the high-est value of 1.07×10-3 S/cm when x was 0.2, then decreased gradually with further increasing Y content. At 600 °C, BaZr0.75Y0.25O3-αdisplayed the highest conductivity, while the conductivity of BaZr0.7Y0.3O3-αwas the highest at 300 °C. The results indicated that there should be an optimum Y doping concentration yielding the highest conductivity at a constant temperature, and the optimum Y doping concentration should increase in the humidity atmosphere as the temperature decreases. So increasing the Y-doping concen-tration is helpful to improve the conductivities of BaZr1-xYxO3-αmaterials at low temperature.